Category: 827-24-7

Samokhvalov, G. I. et al. published their research in Doklady Akademii Nauk SSSR in 1956 | CAS: 827-24-7

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Recommanded Product: 827-24-7

New method of synthesis of polyene ketones with conjugated double bonds was written by Samokhvalov, G. I.;Miropol’skaya, M. A.;Preobrazhenskii, N. A.. And the article was included in Doklady Akademii Nauk SSSR in 1956.Recommanded Product: 827-24-7 This article mentions the following:

Alcs. of propargyl type react with diketene yielding esters of acetoacetic acid, whose Raman spectrum shows a triple bond line (2112 cm.-1) indicating no reaction at the terminal link. Heating to 160-70鎺?eliminates CO2 and yields unsaturated ketones. Condensation of 6-methyl-2-heptenone with C2H2 in Na-liquid NH3 gave 74% 3,7-dimethyloct-6-en-1-yn-3-ol, b6 83-4鎺?nD20 1.4622, d20 0.8861. This with diketene in the presence of a little Na gave 72% Me2C:CHCH2CH2CMe(C椤氬挵H)O2CCH2Ac, b0.2 93-4鎺? nD20 1.4665, d20 0.9879. This heated in N stream to 160-70鎺?3 hrs. gave 61% pseudoionone, b0.1 90-2鎺? absolute maximum 290 m娓? 2,4-dinitrophenylhydrazone, m. 134-6鎺? Fractionation of the latter gave mainly the geometric isomer, m. 147.5-48鎺? and only traces of isomer, m. 119鎺? The isomer found in major amounts corresponds to the structure of geranial form of citral. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7Recommanded Product: 827-24-7).

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Recommanded Product: 827-24-7

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Fisher, Thomas H. et al. published their research in Journal of Organic Chemistry in 1990 | CAS: 827-24-7

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Organo bromine compounds are versatile compounds and are widely used in diverse fields. Organo bromine derivatives are used in the dye sector, as an indicator in analytical chemistry (Bromothymol blue is a popular indicator). When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.COA of Formula: C7H7BrN2O2

Meta-substituent effects on benzyl free-radical stability was written by Fisher, Thomas H.;Dershem, Stephen M.;Prewitt, M. Lynn. And the article was included in Journal of Organic Chemistry in 1990.COA of Formula: C7H7BrN2O2 This article mentions the following:

A series of 5-substituted 3-cyanotoluenes was synthesized, and the relative rates of N-bromosuccinimide bromination were determined in benzene at 80 鎺矯. The resulting 锜?sub>F閳?/sup> values for meta Me, H, Br, NO2, and CN were found to be 0.03, 0.00, -0.03, -0.04, and -0.10, resp. Of these meta substituents, all but Me were found to be destabilizing to the intermediate benzyl free radical. These meta substituent results are consistent with reported 锜?sub>浼?/sub>閳?/sup> and 锜?sub>c閳?/sup> values and cast doubt upon reports that assume meta substituents have no influence on free-radical stability. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7COA of Formula: C7H7BrN2O2).

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Organo bromine compounds are versatile compounds and are widely used in diverse fields. Organo bromine derivatives are used in the dye sector, as an indicator in analytical chemistry (Bromothymol blue is a popular indicator). When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.COA of Formula: C7H7BrN2O2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Samokhvalov, G. I. et al. published their research in Doklady Akademii Nauk SSSR in 1956 | CAS: 827-24-7

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Recommanded Product: 827-24-7

New method of synthesis of polyene ketones with conjugated double bonds was written by Samokhvalov, G. I.;Miropol’skaya, M. A.;Preobrazhenskii, N. A.. And the article was included in Doklady Akademii Nauk SSSR in 1956.Recommanded Product: 827-24-7 This article mentions the following:

Alcs. of propargyl type react with diketene yielding esters of acetoacetic acid, whose Raman spectrum shows a triple bond line (2112 cm.-1) indicating no reaction at the terminal link. Heating to 160-70° eliminates CO2 and yields unsaturated ketones. Condensation of 6-methyl-2-heptenone with C2H2 in Na-liquid NH3 gave 74% 3,7-dimethyloct-6-en-1-yn-3-ol, b6 83-4° nD20 1.4622, d20 0.8861. This with diketene in the presence of a little Na gave 72% Me2C:CHCH2CH2CMe(CCH)O2CCH2Ac, b0.2 93-4°, nD20 1.4665, d20 0.9879. This heated in N stream to 160-70° 3 hrs. gave 61% pseudoionone, b0.1 90-2°, absolute maximum 290 mμ; 2,4-dinitrophenylhydrazone, m. 134-6°. Fractionation of the latter gave mainly the geometric isomer, m. 147.5-48°, and only traces of isomer, m. 119°. The isomer found in major amounts corresponds to the structure of geranial form of citral. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7Recommanded Product: 827-24-7).

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Recommanded Product: 827-24-7

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Fisher, Thomas H. et al. published their research in Journal of Organic Chemistry in 1990 | CAS: 827-24-7

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Organo bromine compounds are versatile compounds and are widely used in diverse fields. Organo bromine derivatives are used in the dye sector, as an indicator in analytical chemistry (Bromothymol blue is a popular indicator). When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.COA of Formula: C7H7BrN2O2

Meta-substituent effects on benzyl free-radical stability was written by Fisher, Thomas H.;Dershem, Stephen M.;Prewitt, M. Lynn. And the article was included in Journal of Organic Chemistry in 1990.COA of Formula: C7H7BrN2O2 This article mentions the following:

A series of 5-substituted 3-cyanotoluenes was synthesized, and the relative rates of N-bromosuccinimide bromination were determined in benzene at 80 °C. The resulting σF• values for meta Me, H, Br, NO2, and CN were found to be 0.03, 0.00, -0.03, -0.04, and -0.10, resp. Of these meta substituents, all but Me were found to be destabilizing to the intermediate benzyl free radical. These meta substituent results are consistent with reported σα• and σc• values and cast doubt upon reports that assume meta substituents have no influence on free-radical stability. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7COA of Formula: C7H7BrN2O2).

2-Bromo-4-methyl-6-nitroaniline (cas: 827-24-7) belongs to organobromine compounds. Organo bromine compounds are versatile compounds and are widely used in diverse fields. Organo bromine derivatives are used in the dye sector, as an indicator in analytical chemistry (Bromothymol blue is a popular indicator). When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.COA of Formula: C7H7BrN2O2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary