Effective fluorescent sensing of Na+ ion by calix[4]arene bearing pyrene and perylene based on energy transfer was written by Nishimura, Yukihiro;Takemura, Tetsuo;Arai, Sadao. And the article was included in ARKIVOC (Gainesville, FL, United States) in 2007.Application of 80480-15-5 The following contents are mentioned in the article:
A new calix[4]arene having pyrene and perylene moieties has been synthesized as a Na+ detectable fluorescent ionophore. When excited at the pyrene moiety (342 nm) of the ionophore, a strong fluorescence emission of the perylene moiety (535 nm) was observed due to energy transfer from the pyrene to perylene. By addition of Na+ at a low concentration in the range of 2.5-10 μM, the fluorescence was remarkably quenched. In contrast to the fluorescent behavior by the ionophore having pyrene and perylene moieties, the excimer emission of a calix[4]arene derivative having two pyrene moieties decreased by the addition of Na+ with a concentration in the range of 50-200 μM. This study involved multiple reactions and reactants, such as 2-Bromo-1-(pyren-1-yl)ethanone (cas: 80480-15-5Application of 80480-15-5).
2-Bromo-1-(pyren-1-yl)ethanone (cas: 80480-15-5) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. alpha-Bromoesters are employed in the Reformatsky reaction for the synthesis of beta-hydroxyesters. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Application of 80480-15-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary