Category: 69361-41-7

Hammoud, Abdelhay’s team published research in Bulletin de la Societe Chimique de France in | CAS: 69361-41-7

Bulletin de la Societe Chimique de France published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, Formula: C7H13BrSi.

Hammoud, Abdelhay published the artcileStereoselective synthesis of 1-acetoxy-7Z,11E-hexadecadiene or angoulure, the sex pheromone of the angoumois grain moth: Sitotrage cerealella Oliv, Formula: C7H13BrSi, the publication is Bulletin de la Societe Chimique de France (1978), 299-303, database is CAplus.

The title compound (I) was prepared by two methods: one involving a Wittig reaction and the other in which a Claisen-Johnson reaction was employed. Thus, (E)-BuCH:CH(CH2)3P+Ph3 Br– condensed with HCO(CH2)5CO2Et to give (E,E)-BuCH:CHCH2CH2CH:CH(CH2)6CO2Et, which was reduced (LiAlH4) and O-acetylated to give I. The alkylation of (E)-HCCCH2CH2CH:CHBu by I(CH2)6OCH(OEt)Me yielded (E)-BuCH:CHCH2CH2CC(CH2)6OH, and O-acetylation and hydrogenation of the product gave I.

Bulletin de la Societe Chimique de France published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, Formula: C7H13BrSi.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary