Category: 629-03-8

Yang, Rui; Dai, Pei; Zhang, Shu; Xu, Ri-Wei; Hong, Song; Lin, Wen-Feng; Wu, Yi-Xian published their research in Polymer in 2021. The article was titled 《In-situ synthesis of cross-linked imidazolium functionalized Poly(styrene-b-isobutylene-b-styrene) for anion exchange membranes》.Product Details of 629-03-8 The article contains the following contents:

The crosslinked imidazolium functionalized anion-exchange membranes is in-situ prepared via reaction of chloromethylated poly(styrene-b-isobutylene-b-styrene) with 1,1′-(1,6-hexanediyl)bisimidazole and N-methylimidazole. The composite membranes of cross-linked imidazolium poly(styrene-b-isobutylene-b-styrene) with a small amount of modified graphene oxide grafted with octadecyl and Pr Ph imidazolium could be further prepared These membranes exhibit significantly high chem. stability and ionic conductivity (σ), marked by low methanol permeability, together with improved dynamic mech. properties. The ionic conductivity of crosslinked imidazolium poly(styrene-b-isobutylene-b-styrene) reaches 2.09 x 10-2 S cm-1 at 80°C by introduction of 0.5 wt% loading of modified graphene oxide. This membrane also behaves an excellent chem. stability and σ can remain ca. 82% of the original value after immerged in strong alk. medium (2 M NaOH) at 60°C for 500 h, which is almost the same as that (ca. 82%) of com. Nafion 115 in acid medium (2 M H2SO4) at 60°C for 500 h. The cross-linked imidazolium poly(styrene-b-isobutylene-b-styrene) is characterized as a promising anion exchange membrane materials in fuel cell for its high ionic conductivity, chem. stability and low methanol permeability. In the experiment, the researchers used 1,6-Dibromohexane(cas: 629-03-8Product Details of 629-03-8)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications; synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.Product Details of 629-03-8

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

The author of 《Optical detection of fe3+ ions in aqueous solution with high selectivity and sensitivity by using sulfasalazine functionalized microgels》 were Ji, Weiming; Zhu, Zumei; Dong, Shunni; Nie, Jingjing; Du, Binyang. And the article was published in Sensors in 2019. Recommanded Product: 1,6-Dibromohexane The author mentioned the following in the article:

A highly selective and sensitive optical sensor was developed to colorimetric detect trace Fe3+ ions in aqueous solution The sensor was the sulfasalazine (SSZ) functionalized microgels (SSZ-MGs), which were fabricated via in-situ quaternization reaction. The obtained SSZ-MGs had hydrodynamic radius of about 259 ± 24 nm with uniform size distribution at 25°C. The SSZ-MG aqueous suspensions can selectively and sensitively response to Fe3+ ions in aqueous solution at 25°C and pH of 5.6, which can be quantified by UV-visible spectroscopy and also easily distinguished by the naked eye. Job’s plot indicated that the molar binding ratio of SSZ moiety in SSZ-MGs to Fe3+ was close to 1:1 with an apparent association constant of 1.72 x 104 M-1. A linear range of 0-12μM with the detection limit of 0.110μM (0.006 mg/L) was found. The obtained detection limit was much lower than the maximum allowance level of Fe3+ ions in drinking water (0.3 mg/L) regulated by the Environmental Protection Agency (EPA) of the United States. The existence of 19 other species of metal ions, namely, Ag+, Li+, Na+, K+, Ca2+, Ba2+, Cu2+, Ni2+, Mn2+, Pb2+, Zn2+, Cd2+, Co2+, Cr3+, Yb3+, La3+, Gd3+, Ce3+-, and Bi3+, did not interfere with the detection of Fe3+ ions. In the experimental materials used by the author, we found 1,6-Dibromohexane(cas: 629-03-8Recommanded Product: 1,6-Dibromohexane)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules; synthesis of water-soluble thermoresponsive polylactides.Recommanded Product: 1,6-Dibromohexane

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

He, Xiaohui; Zou, Jianhua; Guo, Yan; Wang, Kai; Wu, Bin; Wen, Yufei; Zang, Xiujing; Chen, Defu published their research in Polymer in 2021. The article was titled 《Synthesis of halogenated benzonorbornadiene monomer and preparation of self-crosslinking bisimidazole cationic functionalized benzonorbornadiene triblock copolymer anion exchange membrane》.Synthetic Route of C6H12Br2 The article contains the following contents:

In this paper, a series of anion exchange membranes of bisimidazolium functionalized triblock copolymers were synthesized by ring-opening metathesis polymerization of alkyl bromide functionalized benzonorbornadiene derivatives, 1,2-di-Me imidazole and epoxy functionalized norbornene under the action of Grubbs 2nd catalyst. The designed decomposition temperature of the triblock copolymer anion exchange membrane (AEM) exceeded 320 °C, which was much higher than the actual working temperature of anion exchange membrane fuel cell. TEM and AFM characterization proved that the AEM had formed an obvious microphase separation structure. The OH- conductivity of AEM-40 at 80 °C was as high as 56.09 mS cm-1. The single cell performance of the prepared AEM was tested at 60 °C, and we found that AEM-40 reached the highest power d. of 189.1 mW cm-2 at 352.1 mA cm-2. The experimental part of the paper was very detailed, including the reaction process of 1,6-Dibromohexane(cas: 629-03-8Synthetic Route of C6H12Br2)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules; synthesis of water-soluble thermoresponsive polylactides.Synthetic Route of C6H12Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Wholly Visible-Light-Responsive Host-Guest Supramolecular Gels Based on Methoxy Azobenzene and β-Cyclodextrin Dimers》 was written by Yan, Hongchao; Qiu, Yuan; Wang, Jing; Jiang, Qian; Wang, Hong; Liao, Yonggui; Xie, Xiaolin. Formula: C6H12Br2 And the article was included in Langmuir in 2020. The article conveys some information:

Much attention has been paid to construct photoresponsive host-guest supramol. gels; however, red-shifting the responsive wavelength remains a formidable challenge. Here, a wholly visible-light-responsive supramol. gel was fabricated through the host-guest interaction between a β-cyclodextrin (β-CD) dimer and a tetra-ortho-methoxy-substituted azobenzene (mAzo) dimer (binary gelator) in DMSO/H2O (V/V = 8/2). The min. gelation concentration of the low-mol.-weight binary gelator was 6 wt % measured via the tube inversion method. The substituted methoxy groups shifted the responsive wavelengths of trans-mAzo and cis-mAzo to the green and blue light regions, resp. The host-guest interaction between mAzo and β-CD as the driving force for gelation was confirmed using the 1H-NMR and 2D 1H NOESY spectra. The supramol. gel showed good self-supporting ability with a storage modulus higher than 104 Pa. The release of Rhodamine B loaded in the gel as a model drug could be controlled by green light irradiation We envisioned the potential applications of the wholly visible-light-responsive supramol. compounds ranging from biomedical materials to smart materials. In the experimental materials used by the author, we found 1,6-Dibromohexane(cas: 629-03-8Formula: C6H12Br2)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules; synthesis of water-soluble thermoresponsive polylactides.Formula: C6H12Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Category: bromides-buliding-blocksIn 2019 ,《Small antibacterial molecules highly active against drug-resistant Staphylococcus aureus》 was published in MedChemComm. The article was written by Dey, Rajib; De, Kathakali; Mukherjee, Riya; Ghosh, Sreyan; Haldar, Jayanta. The article contains the following contents:

The rapid growth of antibiotic resistance in Staphylococcus aureus coupled with their biofilm forming ability has made the infections difficult to treat with conventional antibiotics. This has created a massive threat towards public health and is a huge concern worldwide. Aiming to address this challenging issue, herein we report a new class of small antibacterial mols. (SAMs) with high antibacterial activity against multidrug-resistant S. aureus. The design principle of the mols. was based on the variation of hydrophobic/hydrophilic balance through incorporation of two quaternary ammonium groups, ethanol moieties, non-peptidic amide bonds and aliphatic chains. The lead compound, identified through a comprehensive anal. of structure-activity relationships, displayed high activity against clin. isolates of methicillin-resistant S. aureus (MRSA) and vancomycin-resistant S. aureus (VRSA) with MIC values in the range of 1-4μg mL-1. More importantly, this compound was capable of killing stationary phase bacteria and disrupting established biofilms of MRSA. Addnl., the compound revealed min. toxicity towards human erythrocytes (HC50 = 577μg mL-1) and did not show significant toxicity towards mammalian cells (MDCK and A549) up to 128 g mL-1. Remarkably, the incorporation of non-peptidic amide bonds made the compounds less susceptible to degradation in human plasma, serum and mouse liver homogenate. Taken together, the results therefore indicate great promise for this class of mols. to be developed as potent antibacterial agents in treating infections caused by drug-resistant S. aureus. In the experiment, the researchers used many compounds, for example, 1,6-Dibromohexane(cas: 629-03-8Category: bromides-buliding-blocks)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules; synthesis of water-soluble thermoresponsive polylactides.Category: bromides-buliding-blocks

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

The author of 《An imidazole coumarin derivative enhances the antiviral response to spring viremia of carp virus infection in zebrafish》 were Liu, Lei; Hu, Yang; Lu, Jianfei; Wang, Gaoxue. And the article was published in Virus Research in 2019. Electric Literature of C6H12Br2 The author mentioned the following in the article:

As an efficient pathogen resulting in economic impact in aquaculture, spring viremia of carp virus (SVCV) causes devastating disease in cyprinids. Based on the previous study that 7-(6-(2-methyl-imidazole))-coumarin (D5) exhibited anti-SVCV activity in fish cells, we hypothesized that D5 may be useful as a potential therapeutic agent for controlling SVCV infection in vivo. In this study, we verified that D5 inhibited SVCV replication in zebrafish, with reducing 22.5% mortality of SVCV-infected fish. Further data suggested that coumarin D5 was more stable with a prolonged inhibitory half-life in the early stage of virus infection (1-4 days). Consistent with above results, D5 decreased the viral titer in fish body and repressed SVCV glycoprotein gene expression in virus sensitive tissues (kidney and spleen) in the early stage of virus infection. In addition, the results replied that D5 elicited an innate immune response in non-viral infected zebrafish by up-regulating the expression of interferon genes (IFNγ, IFNφ1, IFNφ2 and RIG-1). D5 also enhanced the levels of antioxidant-related gene transcription and enzyme activities in SVCV-infected zebrafish, suggesting that D5 exhibited an antioxidant protection on fish by keeping the balance of redox state. Therefore, D5 is a potential therapeutic agent for the devastating fish rhabdovirus infections. The experimental part of the paper was very detailed, including the reaction process of 1,6-Dibromohexane(cas: 629-03-8Electric Literature of C6H12Br2)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications; synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.Electric Literature of C6H12Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Electric Literature of C6H12Br2In 2020 ,《Structure-Adsorption Behavior-Dispersion Property Relationship of Alkyl Chain Cross-Linked Lignosulfonate with Different Molecular Weights》 was published in ACS Omega. The article was written by Hong, Nanlong; Qiu, Xueqing. The article contains the following contents:

The structure-adsorption behavior-dispersion property relationship plays a key role in designing a dispersant or surfactant, such as a coal-water dispersant and a water-reducing agent. In this work, was classified into three fractions with narrow mol. weight distributions via the ultrafiltration method. The adsorption behavior of these three fractions was tested via a quartz crystal microbalance with dissipation monitoring, which showed that the adsorption amounts of the three fractions were far higher than that of sulfomethylated lignin. Fraction-1, with the lowest mol. weight, exhibited the greatest adsorption amount on a Au surface under salt-free conditions. This result illustrates that the alkyl chain is more effective for dispersants with low mol. weight to improve its adsorption amount Fraction-3, with the highest mol. weight, exhibited the greatest adsorption amount on a Au surface under salt-added conditions. This result further illustrates that both the alkyl chain and salt are pos. factors for improving the adsorption amount of dispersants. More importantly, the dispersion stabilization of the TiO2 slurry was significantly improved using the alkAL-S fractions, especially Fraction-3. Based on these results, the alkyl chain crosslinked of lignosulfonate is a promising approach for the industrial applications of lignin as an applicable dispersant.1,6-Dibromohexane(cas: 629-03-8Electric Literature of C6H12Br2) was used in this study.

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules; synthesis of water-soluble thermoresponsive polylactides.Electric Literature of C6H12Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Application of 629-03-8In 2022 ,《Run-and-halt motility of droplets in response to light》 was published in Chem. The article was written by Ryabchun, Alexander; Babu, Dhanya; Movilli, Jacopo; Plamont, Remi; Stuart, Marc C. A.; Katsonis, Nathalie. The article contains the following contents:

Microscopic motility is a property that emerges from systems of interacting mols. Unraveling the mechanisms underlying such motion requires coupling the chem. of mols. with phys. processes that operate at larger length scales. Here, we show that photoactive micelles composed of mol. switches gate the autonomous motion of oil droplets in water. These micelles switch from large trans-micelles to smaller cis-micelles in response to light, and only the trans-micelles are effective fuel for the motion. Ultimately, it is this light that controls the movement of the droplets via the photochem. of the mols. composing the micelles used as fuel. Notably, the droplets evolve pos. photokinetic movement, and in patchy light environments, they preferentially move toward peripheral areas as a result of the difference in illumination conditions at the periphery. Our findings demonstrate that engineering the interplay between mol. photo-chem. and microscopic motility allows designing motile systems rationally. In the experiment, the researchers used 1,6-Dibromohexane(cas: 629-03-8Application of 629-03-8)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications; synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.Application of 629-03-8

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Jiang, Yifei; Chen, Haobin; Men, Xiaoju; Sun, Zezhou; Yuan, Zhen; Zhang, Xuanjun; Chiu, Daniel T.; Wu, Changfeng; McNeill, Jason published an article in 2021. The article was titled 《Multimode Time-Resolved Superresolution Microscopy Revealing Chain Packing and Anisotropic Single Carrier Transport in Conjugated Polymer Nanowires》, and you may find the article in Nano Letters.Safety of 1,6-Dibromohexane The information in the text is summarized as follows:

Here, we developed a novel, multimode superresoln. method to perform full-scale structural mapping and measure the energy landscape for single carrier transport along conjugated polymer nanowires. Through quenching of the local emission, the motion of a single photogenerated hole was tracked using blinking-assisted localization microscopy. Then, utilizing binding and unbinding dynamics of quenchers onto the nanowires, local emission spectra were collected sequentially and assembled to create a superresoln. map of emission sites throughout the structure. The hole polaron trajectories were overlaid with the superresoln. maps to correlate structures with charge transport properties. Using this method, we compared the efficiency of inter- and intrachain hole transport inside the nanowires and for the first time directly measured the depth of carrier traps originated from torsional disorder and chem. defects. The experimental process involved the reaction of 1,6-Dibromohexane(cas: 629-03-8Safety of 1,6-Dibromohexane)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications; synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.Safety of 1,6-Dibromohexane

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2019,RSC Advances included an article by Wang, Caihong; Guan, Xiaoqin; Yuan, Yongli; Wu, Yong; Tan, Shuai. Recommanded Product: 629-03-8. The article was titled 《Polyacrylamide crosslinked by bis-vinylimidazolium bromide for high elastic and stable hydrogels》. The information in the text is summarized as follows:

A series of ionic compounds 1,n-dialkyl-3,3′-bis-l-vinylimidazolium bromide (CnVIM) are prepared and employed to crosslink acrylamide for polyacrylamide (PAAM) hydrogel preparation via in situ solution polymerization The swelling behavior, mech. properties and thermal stability of the prepared CnVIM crosslinked PAAM hydrogels are investigated. CnVIM effectively crosslink the PAAM networks to form porous structures in the hydrogel, which could stably absorb water as much as 75.9 fold in weight without structural degradation The prepared hydrogels could endure compressive stress up to 1.95 MPa and compressive deformation more than 90%. Meanwhile, the CnVIM crosslinked networks show superior thermal stability, and could retain the structural integrity under 150°C for more than 240 h. The swelling degradation resistance, mech. strength and thermal stability of CnVIM crosslinked hydrogels are much better than those of a conventional N,N’-methylenebisacrylamide crosslinked PAAM hydrogel. Using bis-vinylimidazolium bromides as crosslinkers provides an optional strategy for constructing thermally and mech. robust hydrogel networks. In the part of experimental materials, we found many familiar compounds, such as 1,6-Dibromohexane(cas: 629-03-8Recommanded Product: 629-03-8)

1,6-Dibromohexane(cas: 629-03-8) is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are: synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications; synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.Recommanded Product: 629-03-8

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary