Category: 594-81-0

Servis, Kenneth L. published the artcileNMR isotope shifts as a probe of electronic structure, HPLC of Formula: 594-81-0, the publication is Journal of the American Chemical Society (1985), 107(24), 7186-7, database is CAplus.

The β-D isotope effects on the C-13 chem. shifts of 2,3-dimethyl-2-butene, 2,3-dimethyl-2-butene bromonium ion, and 2,3-dimethyl-2-butene mercurinium ion suggests that these cationic derivatives have different electronic structures. The β-D isotope effect in the bromonium ion is pos. (downfield shift) while that in the mercurinium ion is neg. (upfield shift). A comparison with β-D isotope shifts in other cations suggests that the β effects can be related to the electronic structure of these ions.

Journal of the American Chemical Society published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H3ClFNO2, HPLC of Formula: 594-81-0.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary

Windmon, Nicole published the artcileThe role of neat substrates in phase-vanishing and tandem phase-vanishing reactions, Product Details of C6H12Br2, the publication is Tetrahedron Letters (2008), 49(46), 6543-6546, database is CAplus.

Phase-vanishing reactions are triphasic reactions, which involve a reagent, a liquid perfluoroalkane as a phase screen, and a substrate. Aromatization, isomerization, and halogenation of neat substrates under phase-vanishing conditions gave the expected products in good to excellent yields. In tandem single-phase-phase-vanishing reaction, two reactants, placed in the top phase, afforded the intermediate, which in a subsequent phase-vanishing reaction reacted with the reagent from the bottom phase to give the final product. The reaction worked well under solvent-free conditions on liquid substrates and intermediates. With solids, results were better if an addnl. solvent was employed.

Tetrahedron Letters published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C9H6N2O2, Product Details of C6H12Br2.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary

Pels, Kevin published the artcileSolvent-free phase-vanishing reactions with PTFE (Teflon) as a phase screen, Synthetic Route of 594-81-0, the publication is Beilstein Journal of Organic Chemistry (2009), No pp. given, NO. 75, database is CAplus and MEDLINE.

In a solvent-free phase-vanishing reaction with PTFE (polytetrafluoroethylene, Teflon) tape as the phase screen, a thermometer adapter is utilized to insert a PTFE-sealed tube into the vapor phase above the substrate. Besides avoiding use of solvents, the exptl. design is not dependent upon the densities of the reactants and the procedure generates little or no waste while providing the reaction products in high yield and in high purity.

Beilstein Journal of Organic Chemistry published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H12Br2, Synthetic Route of 594-81-0.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary