Category: 523-27-3

In 2022,Wu, Lipeng; Zhang, Kaiming; Shi, Jiaoyan; Wu, Fan; Zhu, Xufei; Dong, Wei; Xie, Aming published an article in Composites, Part B: Engineering. The title of the article was 《Metal/nitrogen co-doped hollow carbon nanorods derived from self-assembly organic nanostructure for wide bandwidth electromagnetic wave absorption》.HPLC of Formula: 523-27-3 The author mentioned the following in the article:

Converting carbonaceous material into heteroatom-doped hollow nanomaterial is a promise route to realize lightweight and high-performance electromagnetic wave absorption (EMA). In this work, a series of metal/nitrogen co-doped hollow carbon nanorods (M-NHCRs, M represent as Fe, Co, Ni) were successfully fabricated via a facile self-assembly template strategy, which refers to self-assembling of 9,10-dibromoanthracene (DBA), surficial modification with polydopamine (PDA) and metal ions, and controlled pyrolysis. Among these M-NHCRs, Co-NHCR exhibits remarkable EMA performance, where the optimal reflection loss (RL) reaches -58.6 dB at a loading ratio of 5 wt%. Moreover, the effective absorption bandwidth (EAB) gets to 7.65 GHz. It is considered that the high-performance EMA should be attributed to the unique hollow structure, excellent conductance loss and improved polarization relaxation. This research not only provides a new idea for the design of lightweight electromagnetic absorbents with broadband efficient absorption, but also broadens the way of synthesizing hollow nanomaterials.9,10-Dibromoanthracene(cas: 523-27-3HPLC of Formula: 523-27-3) was used in this study.

9,10-Dibromoanthracene(cas: 523-27-3) is synthesized by the bromination of anthracene. The bromination reaction is carried out at room temperature using carbon tetrachloride as a solvent. Using 80-85% anthracene as raw material, adding bromine to react for half an hour, the yield is 83-88%.HPLC of Formula: 523-27-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Stepwise Mechanism for the Bromination of Arenes by a Hypervalent Iodine Reagent》 was published in Journal of Organic Chemistry in 2020. These research results belong to Granados, Albert; Shafir, Alexandr; Arrieta, Ana; Cossio, Fernando P.; Vallribera, Adelina. Product Details of 523-27-3 The article mentions the following:

A mild, metal-free bromination method of arenes has been developed using the combination of bis(trifluoroacetoxy)iodobencene and trimethylsilyl bromide. In situ-formed dibromo(phenyl)-λ3-iodane (PhIBr2) is proposed as the reactive intermediate. This methodol. using PIFA/TMSBr has been applied with success to a great number of substrates (25 examples). The treatment of mono-substituted activated arenes led to para-brominated products (2u-z) in excellent 83-96% yields. D. functional theory calculations indicate a stepwise mechanism involving a double bromine addition followed by a type II dyotropic reaction with concomitant re-aromatization of the six-membered ring. The results came from multiple reactions, including the reaction of 9,10-Dibromoanthracene(cas: 523-27-3Product Details of 523-27-3)

9,10-Dibromoanthracene(cas: 523-27-3) can be sublimated and oxidized to generate anthraquinone. Soluble in hot benzene and hot toluene, slightly soluble in alcohol, ether and cold benzene, insoluble in water.Product Details of 523-27-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Wu, Zhenyu; Li, Xinke; Zhao, Yu; Li, Yi; Wei, Kaiqiang; Shi, Hong; Zhang, Tianyang; Huang, Hui; Liu, Yang; Kang, Zhenhui published an article in 2021. The article was titled 《Organic Semiconductor/Carbon Dot Composites for Highly Efficient Hydrogen and Hydrogen Peroxide Coproduction from Water Photosplitting》, and you may find the article in ACS Applied Materials & Interfaces.COA of Formula: C14H8Br2 The information in the text is summarized as follows:

Coprodn. of hydrogen (H2) and hydrogen peroxide (H2O2) from water splitting is one of the most promising ways to alleviate the energy crisis and environmental pollution. Here, we first show the synthesis and photocatalytic property of an organic semiconductor (DAnTMS compound) from 9,10-dibromoanthracene and trimethylsilylacetylene. Then, a metal-free photocatalyst of a DAnTMS/carbon dot (DAnTMS/CD) composite was designed and fabricated, which achieved the efficient photocatalytic production of H2 and H2O2 without usage of any organic solvents and sacrificial agents. Under visible light, the DAnTMS/CD composite could produce H2O2 with a maximum rate of 396.7 μmol g-1 h-1 and H2 with a maximum rate of 365.0 μmol g-1 h-1 in pure water. Transient photovoltage tests showed that CDs changed the interface electron transfer kinetics and served as the active site for highly efficient H2 evolution. This work provided a deep insight into the function of CDs in regulating the catalytic property of organic photocatalysts. After reading the article, we found that the author used 9,10-Dibromoanthracene(cas: 523-27-3COA of Formula: C14H8Br2)

9,10-Dibromoanthracene(cas: 523-27-3) is a dibrominated polycyclic aromatic hydrocarbon (PAH). 9,10-Dibromoanthracene is often used as an energy acceptor and activator in reactions that produce chemiluminescence.COA of Formula: C14H8Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2022,Zhang, Wei; Luo, Yang; Jia, Meng-Hao; Ni, Xin-Long; Tao, Zhu; Xiao, Chao-Da; Xiao, Xin published an article in Sensors and Actuators, B: Chemical. The title of the article was 《An efficient supramolecular artificial light-harvesting system based on twisted cucurbit[15]uril and cucurbit[10]uril for live cell imaging》.Electric Literature of C14H8Br2 The author mentioned the following in the article:

The construction of highly efficient artificial light-harvesting systems in aqueous solutions is still challenging. Herein, we reported a new light-harvesting system based on the supramol. combination of twisted cucurbit[15]uril (tQ[15]), cucurbit[10]uril (Q[10]), and an anthracene derivative (APy) with aggregation-induced emission (AIE) properties. The Q[n]-based linear supramol. polymer, APy@tQ[15]@Q[10], was constructed through a two-step assembly strategy. Subsequently, a highly efficient artificial light-harvesting system with relatively high antenna effect and energy transfer efficiency was successfully constructed through non-covalent interactions between Rhodamine B (RB, acceptor) and the APy@tQ[15]@Q[10] (donor). The resulting system was compatible with HeLa cells and could be used for live-cell imaging in the red channel. This supramol. assembly strategy has not only produced a highly efficient light-harvesting system but also expands the application of Q[n]s in the biomedical field. After reading the article, we found that the author used 9,10-Dibromoanthracene(cas: 523-27-3Electric Literature of C14H8Br2)

9,10-Dibromoanthracene(cas: 523-27-3) is synthesized by the bromination of anthracene. The bromination reaction is carried out at room temperature using carbon tetrachloride as a solvent. Using 80-85% anthracene as raw material, adding bromine to react for half an hour, the yield is 83-88%.Electric Literature of C14H8Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2022,Scheurle, Patricia I.; Maehringer, Andre; Haug, Tabea; Biewald, Alexander; Axthammer, Daniel; Hartschuh, Achim; Harms, Lena; Wittstock, Gunther; Medina, Dana D.; Bein, Thomas published an article in Crystal Growth & Design. The title of the article was 《Helical Anthracene-Ethyne-Based MOF-74 Analogue》.Safety of 9,10-Dibromoanthracene The author mentioned the following in the article:

A flexible, electron-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topol. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphol., exhibiting visible light absorption and photoluminescence. In the experiment, the researchers used 9,10-Dibromoanthracene(cas: 523-27-3Safety of 9,10-Dibromoanthracene)

9,10-Dibromoanthracene(cas: 523-27-3) is synthesized by the bromination of anthracene. The bromination reaction is carried out at room temperature using carbon tetrachloride as a solvent. Using 80-85% anthracene as raw material, adding bromine to react for half an hour, the yield is 83-88%.Safety of 9,10-Dibromoanthracene

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Perfluoroalkylated anthracene endoperoxide: Synthesis, characterization, crystal structure analysis, and computational insights》 was written by Putta, Anjaneyulu; Sykes, Andrew G.; Sun, Haoran. Formula: C14H8Br2 And the article was included in Journal of Fluorine Chemistry in 2020. The article conveys some information:

Aromatic endoperoxides serve as important intermediate species toward generating singlet state oxygen, which is key to photodynamic therapy applications. Gaining insights for fine-tuning endoperoxide stability and degree of oxygen-oxygen bond activation is of fundamental and practical interest for the chem. and medicinal communities. We report here that 9,10-bisperfluorooctyl-anthracene, upon exposing to light and air, is almost quant. converted to 9,10-bisperfluorooctyl-anthracene endoperoxide (compound 1) at room temperature 1H NMR spectra and the X-ray crystal structure revealed that the resulting compound 1 is stable at room temperature without further decomposition The crystal structure anal. showed that the compound 1 is stabilized by F···O intramol. interactions along with F···F, F···H and F···C intermol. interactions. DFT calculations further indicate that the degree of oxygen-oxygen bond activation in anthracene endoperoxides, reflected as changes of O-O, C-O bond distances, may not solely depend on the electronic effect of substituents at the 9,10- positions. This uncertainty warrants further investigation both exptl. and computationally. The experimental part of the paper was very detailed, including the reaction process of 9,10-Dibromoanthracene(cas: 523-27-3Formula: C14H8Br2)

9,10-Dibromoanthracene(cas: 523-27-3) is a dibrominated polycyclic aromatic hydrocarbon (PAH). 9,10-Dibromoanthracene is often used as an energy acceptor and activator in reactions that produce chemiluminescence.Formula: C14H8Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Hussain, Waseem A.; Plunkett, Kyle N. published their research in Journal of Organic Chemistry in 2021. The article was titled 《Benzodithiophene-Fused Cyclopentannulated Aromatics via a Palladium-Catalyzed Cyclopentannulation and Scholl Cyclodehydrogenation Strategy》.Reference of 9,10-Dibromoanthracene The article contains the following contents:

The synthesis of a new class of cyclopenta-fused polyaromatic hydrocarbon (CP-PAH) incorporating fused benzodithiophene subunits was reported. These CP-PAHs were prepared utilizing a two-step process involving a palladium catalyzed cyclopentannulation followed by a Scholl cyclodehydrogenation. This work broadens the scope of annulation chem. by employing 1,2-bis(5-hexylthiophen-3-yl)ethyne and dibromoaryl derivatives based on 9,10-dibromoanthracene, 3,8-dibromopyrene, and 3,9-dibromoperylene. Scholl cyclodehydrogenation of the pendant thiophene units provided access to the π-extended polyaromatic systems that possess helicene-like fragments. The anthracene-based CP-PAH was contorted owing to [5]helicene-like arrangements, while the pyrene- and perylene-based systems were essentially planar. The fully conjugated small mols. give low optical gaps (1.7-2.1 eV) with broad light absorption. The HOMO and LUMO energies of the CP-PAHs were found to be in the range of -5.48 to -5.05 eV and -3.48 to -3.14 eV. Finally, the anthracene-based CP-PAH was found to be a p-type semiconductor when tested in an organic field effect transistor.9,10-Dibromoanthracene(cas: 523-27-3Reference of 9,10-Dibromoanthracene) was used in this study.

9,10-Dibromoanthracene(cas: 523-27-3) can be sublimated and oxidized to generate anthraquinone. Soluble in hot benzene and hot toluene, slightly soluble in alcohol, ether and cold benzene, insoluble in water.Reference of 9,10-Dibromoanthracene

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

HPLC of Formula: 523-27-3In 2022 ,《Four- and two-armed hetero porphyrin dimers: their specific recognition and self-sorting behaviours》 appeared in Organic & Biomolecular Chemistry. The author of the article were Ueda, Masahiro; Kimura, Masaki; Miyagawa, Shinobu; Naito, Masaya; Takaya, Hikaru; Tokunaga, Yuji. The article conveys some information:

In this study we self-assembled the four-armed porphyrin hetero dimer capsule Cap4, stabilized through amidinium-carboxylate salt bridges, in CH2Cl2 and CHCl3. The dimer capsule Cap4 was kinetically and thermodynamically more stable than the corresponding two-armed dimer Cap2. The number of arms strongly influenced their recognition behavior; guests possessing small aromatic faces (e.g., 1,3,5-trinitrobenzene) preferred residing in the cavity of the two-armed capsule Cap2, rather than in Cap4, both thermodynamically and kinetically; in contrast, large aromatic guests (e.g., 9,10-dibromoanthracene) were encapsulated predominantly by Cap4 because of favorable entropic effects. The number of arms enabled self-sorting behavior of the dimer formation; complexation studies using an equimolar mixture of the four porphyrin constituents of the two capsules revealed the quant. formation of the corresponding dimers Cap2 and Cap4. Furthermore, we examined the specific mol. recognition of Cap2 and Cap4; NMR experiments of mixtures of Cap2 and Cap4 in the presence of favorable guests for Cap2 and Cap4 revealed that these guest mols. were encapsulated selectively by their preferred hosts. In the experimental materials used by the author, we found 9,10-Dibromoanthracene(cas: 523-27-3HPLC of Formula: 523-27-3)

9,10-Dibromoanthracene(cas: 523-27-3) is a dibrominated polycyclic aromatic hydrocarbon (PAH). 9,10-Dibromoanthracene is often used as an energy acceptor and activator in reactions that produce chemiluminescence.HPLC of Formula: 523-27-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Passive air sampling of halogenated polycyclic aromatic hydrocarbons in the largest industrial city in Korea: Spatial distributions and source identification》 was written by Vuong, Quang Tran; Kim, Seong-Joon; Nguyen, Tuyet Nam Thi; Thang, Phan Quang; Lee, Sang-Jin; Ohura, Takeshi; Choi, Sung-Deuk. Recommanded Product: 9,10-Dibromoanthracene And the article was included in Journal of Hazardous Materials in 2020. The article conveys some information:

Some halogenated polycyclic aromatic hydrocarbons (Halo-PAHs) are known to be more toxic than their corresponding parent PAHs, but studies on Halo-PAHs have been somewhat limited. In this study, passive air samplers were used to monitor Halo-PAH and PAH contamination at 20 sampling sites in Ulsan, one of the largest industrial cities in South Korea. The mean concentrations of Σ24 ClPAHs, Σ11 BrPAHs, and Σ13 PAHs were 207 pg/m3, 84 pg/m3, and 26 ng/m3, resp. Industrial areas displayed higher concentrations of both Halo-PAHs and PAHs than urban and rural areas. Strong correlations between energetically unfavorable Halo-PAHs and their corresponding parent PAHs suggest that the main formation mechanism of Halo-PAHs is not direct halogenation of PAHs. Low mol. weight Halo-PAHs with one halogen atom and their parent PAHs were dominant. The profiles of ClPAHs and BrPAHs in petrochem., automobile, shipbuilding, and non-ferrous industrial complexes were distinguished. The toxicity equivalency quantities (TEQs) of ClPAHs, BrPAHs, and PAHs at the industrial sites also showed the highest values of 4.2, 0.5, and 18.3 pg-TEQ/m3, resp., reflecting the high toxicity of Halo-PAHs. To the best of our knowledge, this is the first study reporting atm. levels of both ClPAHs and BrPAHs using passive air samplers. The results came from multiple reactions, including the reaction of 9,10-Dibromoanthracene(cas: 523-27-3Recommanded Product: 9,10-Dibromoanthracene)

9,10-Dibromoanthracene(cas: 523-27-3) is a dibrominated polycyclic aromatic hydrocarbon (PAH). 9,10-Dibromoanthracene is often used as an energy acceptor and activator in reactions that produce chemiluminescence.Recommanded Product: 9,10-Dibromoanthracene

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Multi-fold Sonogashira coupling: a new and convenient approach to obtain tetraalkynyl anthracenes with tunable photophysical properties》 was written by Islam, Khadimul; Narjinari, Himani; Bisarya, Akshara; Kumar, Akshai. Computed Properties of C14H8Br2 And the article was included in Organic & Biomolecular Chemistry in 2021. The article conveys some information:

For the first time, a direct single-step one-pot route to access nine new sym. tetraalkynylated anthracenes via Pd(CH3CN)2Cl2/cataCXiumA catalyzed tetra-fold Sonogashira coupling was reported. Five of these tetraalkynylated anthracenes was crystallog. characterized, with two of them exhibiting multiple interactions that significantly shorten the inter-planar distances in the solid-state structure. The rich photophys. properties exhibited by these mols. hold immense promise for future applications in sensors and optoelectronic devices. Two of the considered tetraalkynylated anthracenes comprising a D-π-A-π-D motif demonstrate solvatochromism and halochromism, with one of them showing a low bandgap of 1.79 eV. The remaining compounds demonstrate bandgaps in the range of 1.79-2.04 eV. In addition to this study using 9,10-Dibromoanthracene, there are many other studies that have used 9,10-Dibromoanthracene(cas: 523-27-3Computed Properties of C14H8Br2) was used in this study.

9,10-Dibromoanthracene(cas: 523-27-3) can be sublimated and oxidized to generate anthraquinone. Soluble in hot benzene and hot toluene, slightly soluble in alcohol, ether and cold benzene, insoluble in water.Computed Properties of C14H8Br2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary