Category: 2675-79-8

《Triphenylamine- and triazine-containing hydrogen bonded complexes: liquid crystalline supramolecular semiconductors》 was written by Feringan, Beatriz; Termine, Roberto; Golemme, Attilio; Granadino-Roldan, Jose M.; Navarro, Amparo; Gimenez, Raquel; Sierra, Teresa. Formula: C9H11BrO3This research focused ontriphenylamine triazine complex preparation liquid crystal supramol semiconductor. The article conveys some information:

It was reported that triphenylamine liquid crystals can attain very high hole mobility values in a hexagonal columnar mesophase, up to μ ≈ 5 cm2 V-1 s-1. The columnar liquid crystalline phase was obtained by a proper design of a supramol. mesogen, and this was unprecedented for triphenylamine liquid crystals. In fact, the supramols. were formed by hydrogen-bonded 1 : 3 complexes of a star-shaped triazine core and three triphenylamine peripheral units. The resulting hexagonal columnar mesophase acted as a successful scaffold that confines TPA units at the periphery of columns. Challenging DFT theor. investigations into a model based on such supramol. systems involving a large number of atoms were undertaken to explore the stability and geometry of the complexes and their electronic properties. After reading the article, we found that the author used 1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8Formula: C9H11BrO3)

1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.Formula: C9H11BrO31-Bromo-3,4,5-trimethoxybenzene can be used to synthesize analogs of HA14-1, which shows promising anticancer properties.

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《The liquid crystal Click procedure for oligothiophene-tethered phthalocyanines – self-assembly, alignment and photocurrent》 was written by Dechant, Moritz; Lehmann, Matthias; Uzurano, Genya; Fujii, Akihiko; Ozaki, Masanori. Synthetic Route of C9H11BrO3This research focused onzinc phthalocyanine oligothiophene tether preparation photocurrent property; fluorescence thermotropic liquid crystal zinc phthalocyanine oligothiophene tether. The article conveys some information:

A series of star-shaped liquid crystals (LCs) with a phthalocyanine donor core, oligothiophene antennae and fullerene acceptors have been successfully prepared This hierarchical self-assembly results in a nanosegregated helical donor-acceptor-antennae LC-system promoted by the recently discovered Click procedure. This model system reveals all photophys. prerequisites for energy conversion, charge generation and transport. Uniform amorphous thin films of 150 nm could be produced by bar-coating. Annealing did not only induce the formation of columns via the Click procedure but also partially homeotropically aligned the non-clearing sample in a sandwich geometry (ITO and Ag/MoO3). This has been confirmed by microscopic studies and the measurement of photocurrent, which increased by a factor of 300 after the annealing step. In the experiment, the researchers used 1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8Synthetic Route of C9H11BrO3)

1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.Synthetic Route of C9H11BrO31-Bromo-3,4,5-trimethoxybenzene can be used to synthesize analogs of HA14-1, which shows promising anticancer properties.

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Parker, Rachel R.; Liu, Denghui; Yu, Xiankang; Whitwood, Adrian C.; Zhu, Weiguo; Williams, J. A. Gareth; Wang, Yafei; Lynam, Jason M.; Bruce, Duncan W. published an article in 2021. The article was titled 《Synthesis, mesomorphism, photophysics and device performance of liquid-crystalline pincer complexes of gold(III)》, and you may find the article in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices.Related Products of 2675-79-8 The information in the text is summarized as follows:

Emissive gold(III) complexes of pincer 2,6-diphenylpyridines also bearing a phenylacetylide ligand have been modified at both the pincer and phenylacetylide to confer liquid crystalline properties, with most complexes showing a columnar hexagonal phase in the condensed phase. Solution NMR studies show a preferred orientation for self-association, consistent with structural parameters in the liquid crystal phase obtained by X-ray methods. While the pattern of substitution of the phenylacetylide has no discernible effect on the photophysics, when two alkoxy chains are attached to the pincer ligands, photoluminescence quantum yields (PLQY) of around 3% are found, whereas when four alkoxy chains are attached the PLQY increases significantly to 36%. Insight from computational chem. indicated that the incorporation of the alkoxy donor groups raises the energy of the pincer-based HOMO-1 orbital, with a concomitant lowering of the LUMO ← HOMO-1 transition energy, consistent with an exptl. observed red shift. The gold complexes were fabricated into OLED devices using solution processing methods, being doped into the emissive layer at 5%, leading to external quantum efficiencies of up to 7.14%, values that compare well with those of related complexes in the literature. In addition to this study using 1-Bromo-3,4,5-trimethoxybenzene, there are many other studies that have used 1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8Related Products of 2675-79-8) was used in this study.

1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.Related Products of 2675-79-81-Bromo-3,4,5-trimethoxybenzene can be used to synthesize N,N′-diarylated indolo[3,2-b]carbazole derivatives, which can find applications in electrophotography.

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary