Category: 170434-11-4

Graphene Oxide-Supported Hypervalent Organoiodine (III): Recyclable Reagent for Selective and Metal-Free Oxidation of Alcohols was written by Ghanbari, Nastaran;Ghafuri, Hossein;Zand, Hamid Reza Esmaili. And the article was included in ChemistrySelect in 2018.Electric Literature of C7H7BrO2 This article mentions the following:

In this research, main emphasis has been placed on the oxidizing properties of graphene oxide (GO) and hypervalent organoiodine (III) (HVI) and their oxidizing effect in GO-HVI. GO-HVI as a metal-free, environmentally-friendly, recyclable and efficient heterogeneous reagent was synthesized and completely characterized by Fourier transform IR spectroscopy (FT-IR), energy dispersive X-ray (EDX), field emission SEM (FE-SEM), X-ray diffraction, and at. force microscopy (AFM). The synthesized GO-HVI was used to achieve an effective and selective method for oxidation of various alcs. All substituted alcs. were oxidized in good to excellent yields under mild conditions at room temperature The oxidizing ability of GO-HVI was higher in comparison with starting GO and HVI. This GO-HVI have great stability and could be recycled six times without noteworthy loss of activity. In the experiment, the researchers used many compounds, for example, 5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4Electric Literature of C7H7BrO2).

5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Electric Literature of C7H7BrO2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Syntheses of polyfunctionalized resveratrol derivatives using Wittig and Heck protocols was written by Chalal, Malik;Vervandier-Fasseur, Dominique;Meunier, Philippe;Cattey, Helene;Hierso, Jean-Cyrille. And the article was included in Tetrahedron in 2012.Name: 5-Bromo-2-(hydroxymethyl)phenol This article mentions the following:

Improved protocols for Wittig reaction and palladium-catalyzed Heck coupling give expedient access to a series of unprecedented polyfunctionalized artificial-resveratrol derivatives, e.g., I. In the modified Wittig protocol, trimethylsilyl was used as a highly valuable protective group of the phenolic functions of starting aromatic materials. A clean O-alkylation of hydroxylated stilbenes with ethylene carbonate was also conducted. Thus, Wittig reaction followed by hydroxyethylation take place one-pot with only carbon dioxide as waste. Addnl., a palladium-catalyzed Heck coupling strategy was developed by using ferrocenyl phosphane ligands, and multi-functionalized hydroxylated stilbenes were obtained without the need of any protection/deprotection sequence. Up to six functional groups are introduced by these procedures, which limit the number of reaction steps, the waste toxicity, and the use of costly reagents. In the experiment, the researchers used many compounds, for example, 5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4Name: 5-Bromo-2-(hydroxymethyl)phenol).

5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Name: 5-Bromo-2-(hydroxymethyl)phenol

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Graphene Oxide-Supported Hypervalent Organoiodine (III): Recyclable Reagent for Selective and Metal-Free Oxidation of Alcohols was written by Ghanbari, Nastaran;Ghafuri, Hossein;Zand, Hamid Reza Esmaili. And the article was included in ChemistrySelect in 2018.Electric Literature of C7H7BrO2 This article mentions the following:

In this research, main emphasis has been placed on the oxidizing properties of graphene oxide (GO) and hypervalent organoiodine (III) (HVI) and their oxidizing effect in GO-HVI. GO-HVI as a metal-free, environmentally-friendly, recyclable and efficient heterogeneous reagent was synthesized and completely characterized by Fourier transform IR spectroscopy (FT-IR), energy dispersive X-ray (EDX), field emission SEM (FE-SEM), X-ray diffraction, and at. force microscopy (AFM). The synthesized GO-HVI was used to achieve an effective and selective method for oxidation of various alcs. All substituted alcs. were oxidized in good to excellent yields under mild conditions at room temperature The oxidizing ability of GO-HVI was higher in comparison with starting GO and HVI. This GO-HVI have great stability and could be recycled six times without noteworthy loss of activity. In the experiment, the researchers used many compounds, for example, 5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4Electric Literature of C7H7BrO2).

5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Electric Literature of C7H7BrO2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Syntheses of polyfunctionalized resveratrol derivatives using Wittig and Heck protocols was written by Chalal, Malik;Vervandier-Fasseur, Dominique;Meunier, Philippe;Cattey, Helene;Hierso, Jean-Cyrille. And the article was included in Tetrahedron in 2012.Name: 5-Bromo-2-(hydroxymethyl)phenol This article mentions the following:

Improved protocols for Wittig reaction and palladium-catalyzed Heck coupling give expedient access to a series of unprecedented polyfunctionalized artificial-resveratrol derivatives, e.g., I. In the modified Wittig protocol, trimethylsilyl was used as a highly valuable protective group of the phenolic functions of starting aromatic materials. A clean O-alkylation of hydroxylated stilbenes with ethylene carbonate was also conducted. Thus, Wittig reaction followed by hydroxyethylation take place one-pot with only carbon dioxide as waste. Addnl., a palladium-catalyzed Heck coupling strategy was developed by using ferrocenyl phosphane ligands, and multi-functionalized hydroxylated stilbenes were obtained without the need of any protection/deprotection sequence. Up to six functional groups are introduced by these procedures, which limit the number of reaction steps, the waste toxicity, and the use of costly reagents. In the experiment, the researchers used many compounds, for example, 5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4Name: 5-Bromo-2-(hydroxymethyl)phenol).

5-Bromo-2-(hydroxymethyl)phenol (cas: 170434-11-4) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Name: 5-Bromo-2-(hydroxymethyl)phenol

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary