Organic compounds having carbon bonded to bromine are called organic bromides. 1575-37-7, formula is C6H7BrN2, Name is 4-Bromobenzene-1,2-diamine. Depending on the type of carbon to which the bromine is bonded, organic bromide could be alkyl, alkenyl, alkynyl, or aryl. Recommanded Product: 4-Bromobenzene-1,2-diamine.
Singh, Pooja S.;Badani, Purav M.;Kamble, Rajesh M. research published 《 Blue-orange emitting carbazole based donor-acceptor derivatives: Synthesis and studies of modulating acceptor unit on opto-electrochemical and theoretical properties》, the research content is summarized as follows. In order to demonstrate an effect of varying acceptor unit on optoelectronic properties of Donor-Acceptor (D-A) assembly, we herein designed and synthesized C-N coupled, carbazole based dyes 1-8 by employing Buchwald-Hartwig coupling amination reaction and fully characterized by spectroscopic methods. Presence of intramol. charge transfer (ICT) transitions (λmax = 403-467 nm) in absorption spectra of all dyes reminiscent D-A assembly in it and emit in blue-yellow region (λemm = 467-565 nm) in solution state with marked pos. solvatochromism. The photophys. studies of some of the dyes in different THF/water mixtures revealed aggregation-induced emission (AIE) feature with the nanoparticles formation, as confirmed by dynamic light scattering (DLS) technique. The HOMO (-5.42 to -5.74 eV) and LUMO (-3.03 to -3.50 eV) energy level of these mols. measured by cyclic voltammetry suggest electron transporting property in it. Further, DFT/TDDFT calculation of dyes, indicate quite comparable theor. and exptl. photophys. and electrochem. data. Moreover, calculated singlet (S1) and triplet (T1) excitation energy levels by DFT/B3LYP/6-311 G+(d,p) shows small ΔEST value for some dyes and hence called as TADF emitters. Thus obtained all optoelectrochem. properties of dyes propose its potential use in optoelectronic devices and in biosensing.
1575-37-7, 4-Bromo-1,2-diaminobenzene can be obtained from 1,2-diaminobenzene via acetylation followed by bromination and alkaline hydrolysis.
4-Bromobenzene-1,2-diamine, also known as 4-Bromobenzene-1,2-diamine, is a useful research compound. Its molecular formula is C6H7BrN2 and its molecular weight is 187.04 g/mol. The purity is usually 95%.
4-Bromo-1,2-diaminobenzene is a dye that is used in diagnostic
procedures to detect the presence of amide groups. 4-Bromo-1,2-diaminobenzene can be used as an inhibitor for cationic polymerization reactions. It also has tuberculostatic activity and inhibits the growth of Mycobacterium tuberculosis. This compound reacts with aniline to form a benzimidazole derivative that contains a reactive amine group. The reaction between this amine group and different electrophiles generates benzimidazole compounds with different properties that are useful in nucleophilic attack reactions. The reaction between 4-bromo-1,2-diaminobenzene and methyl ethyl sulfide produces a luminescent probe that can be used to detect hydrogen bonds., Recommanded Product: 4-Bromobenzene-1,2-diamine
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary