Category: 1530-32-1

The author of 《Synthesis of a C1-C12 Fragment of Gulmirecin B》 were Rengarasu, Rathikrishnan; Maier, Martin E.. And the article was published in Synlett in 2019. Application of 1530-32-1 The author mentioned the following in the article:

The synthesis of a C1-C14 fragment I of the macrolide antibiotic gulmirecin B through formation of the C7-C8 bond by addition of a vinyllithium intermediate to a C1-C7 aldehyde was investigated. This crucial coupling was successful with a vinyllithium reagent corresponding to a C8-C12 fragment. The C8-C12 vinyl bromide II was prepared from L-malic acid. The C1-C7 aldehyde III building block was synthesized from hex-5-enoic acid by using an Evans alkylation, a cross-metathesis, and an asym. dihydroxylation as key steps. In the experimental materials used by the author, we found Ethyltriphenylphosphonium bromide(cas: 1530-32-1Application of 1530-32-1)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. CatOnium ETPB is also used as catalysts in the synthesis of certain organic compounds.Application of 1530-32-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Zhang, Jian; Mu, Keman; Yang, Peng; Feng, Xinqian; Zhang, Di; Fan, Xiangyu; Wang, Qiantao; Mao, Shengjun published their research in Bioorganic Chemistry in 2021. The article was titled 《Synthesis, antiepileptic effects, and structure-activity relationships of α-asarone derivatives: In vitro and in vivo neuroprotective effect of selected derivatives》.SDS of cas: 1530-32-1 The article contains the following contents:

In the present study, we compared the antiepileptic effects of α-asarone derivatives to explore their structure-activity relationships using the PTZ-induced seizure model. Our research revealed that electron-donating methoxy groups in the 3,4,5-position on Ph ring increased antiepileptic potency but the placement of other groups at different positions decreased activity. Besides, in allyl moiety, the optimal activity was reached with either an allyl or a 1-butenyl group in conjugation with the benzene ring. The compounds 5 (I) and 19 (II) exerted better neuroprotective effects against epilepsy in vitro (cell) and in vivo (mouse) models. This study provides valuable data for further exploration and application of these compounds as potential anti-seizure medicines. In addition to this study using Ethyltriphenylphosphonium bromide, there are many other studies that have used Ethyltriphenylphosphonium bromide(cas: 1530-32-1SDS of cas: 1530-32-1) was used in this study.

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.SDS of cas: 1530-32-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Guo, Sheng-Qiang; Yang, Hui-Qing; Jiang, Yu-Zhen; Wang, Ai-Lian; Xu, Guo-Qiang; Luo, Yong-Chun; Chen, Zhao-Xu; Zheng, Haixue; Xu, Peng-Fei published an article in 2022. The article was titled 《Organophotoredox catalytic four-component radical-polar crossover cascade reactions for the stereoselective synthesis of β-amido sulfones》, and you may find the article in Green Chemistry.Electric Literature of C20H20BrP The information in the text is summarized as follows:

Herein, a green and reliable strategy for the diastereoselective synthesis of β-amido sulfones R1S(O)2CH(R2)CH(Ar)NHC(O)R3 (R1 = Me, 4-methylphenyl, naphth-2-yl, etc.; R2 = H, Me, Et, Pr, isopropyl; Ar = Ph, 3,4-dichlorophenyl, naphth-2-yl, etc.; R3 = Me, cyclopopyl, Ph, etc.) and I through organophotoredox catalytic four-component radical-polar crossover cascade reactions was reported. This transformation features excellent atom-, step-, and redox economy and diastereoselectivity. Moreover, DFT calculation studies were performed to provide some insights into the origin of diastereoselectivity. In addition to this study using Ethyltriphenylphosphonium bromide, there are many other studies that have used Ethyltriphenylphosphonium bromide(cas: 1530-32-1Electric Literature of C20H20BrP) was used in this study.

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.Electric Literature of C20H20BrP

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2022,Noten, Efrey A.; McAtee, Rory C.; Stephenson, Corey R. J. published an article in Chemical Science. The title of the article was 《Catalytic intramolecular aminoarylation of unactivated alkenes with aryl sulfonamides》.Recommanded Product: 1530-32-1 The author mentioned the following in the article:

In this work, an intramol. alkene aminoarylation cascade that exploits the electrophilicity of a nitrogen-centered radical to form a C-N bond, then repurposes the nitrogen atom’s sulfonyl activating group as a traceless linker to form a subsequent C-C bond was disclosed. This photoredox catalysis protocol enabled the preparation of densely substituted arylethylamines I [R1 = H, Me; R2 = H, Me, i-Pr, BrCH2CH2, Ph; R1R2 = H2COCH2, (CH2C)3, (CH2C)5; R3= 2-pyridyl, 2,6-di-FC6H3, 2,4,6-tri-ClC6H2, etc.] from com. abundant aryl sulfonamides and unactivated alkenes under mild conditions. Reaction optimization, scope, mechanism, and synthetic applications were discussed. In the experiment, the researchers used many compounds, for example, Ethyltriphenylphosphonium bromide(cas: 1530-32-1Recommanded Product: 1530-32-1)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.Recommanded Product: 1530-32-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Asymmetric construction of acyclic quaternary stereocenters via direct enantioselective additions of α-alkynyl ketones to allenamides》 was written by Wang, Jiawen; He, Faqian; Yang, Xiaoyu. Application of 1530-32-1 And the article was included in Nature Communications in 2021. The article conveys some information:

Acyclic quaternary stereocenters are widely present in a series of biol. active natural products and pharmaceuticals. However, development of highly efficient asym. catalytic methods for the construction of these privileged motifs represents a longstanding challenge in organic synthesis. Herein, an efficient chiral phosphoric acid catalyzed direct asym. addition of α-alkynyl acyclic ketones with allenamides has been developed, furnishing the acyclic all-carbon quaternary stereocenters with excellent regioselectivities and high enantioselectivities. Extensive and detailed exptl. mechanistic studies were performed to investigate the mechanism of this reaction. Despite a novel covalent allyl phosphate intermediate was found in these reactions, further studies indicated that a SN2-type mechanism with the ketone nucleophiles is not very possible. Instead, a more plausible mechanisml involving the elimination of the allyl phosphate to give the α,β-unsaturated iminium intermediate, which underwent the asym. conjugate addition with the enol form of ketone nucleophiles under chiral anion catalysis, was proposed. In virtue of the fruitful functional groups bearing in the chiral products, the diverse derivatizations of the chiral products provided access to a wide array of chiral scaffolds with quaternary stereocenters. In addition to this study using Ethyltriphenylphosphonium bromide, there are many other studies that have used Ethyltriphenylphosphonium bromide(cas: 1530-32-1Application of 1530-32-1) was used in this study.

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.Application of 1530-32-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2022,Tandekar, Kesar; Tripathi, Anjali; Prasad, Muvva D.; Supriya, Sabbani published an article in Materials Advances. The title of the article was 《Keggin based self-assembled mesoporous materials for capture of selective guest molecules》.Quality Control of Ethyltriphenylphosphonium bromide The author mentioned the following in the article:

A series of self-assembled mesoporous materials, compounds 1-9, of the type [RPPh3]n[XM12O40] (R = Ph, Me, Et; n = 3 or 4; X = P, Si; M = Mo, W) composed of Keggin anions and phosphonium cations have been fabricated and characterized. These thermally stable hybrid materials show selective reversible uptake of non-polar mols. such as iodine and carbon disulfide under ambient conditions. The resultant porosity is attributed to the self-assembling of the cations on the surface of the Keggin anion such that the pores are lined with the phosphonium cations rendering them hydrophobhic. The present work explores the spontaneous self-assembly process of POM integrated mesoporous compounds stabilized via non-covalent interactions and their potential applications as adsorbing materials. In the experimental materials used by the author, we found Ethyltriphenylphosphonium bromide(cas: 1530-32-1Quality Control of Ethyltriphenylphosphonium bromide)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. CatOnium ETPB is also used as catalysts in the synthesis of certain organic compounds.Quality Control of Ethyltriphenylphosphonium bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Alkyl vs. aryl modifications: a comparative study on modular modifications of triphenylphosphonium mitochondrial vectors》 was written by Ong, How Chee; Coimbra, Joao T. S.; Kwek, Germain; Ramos, Maria J.; Xing, Bengang; Fernandes, Pedro A.; Garcia, Felipe. Application In Synthesis of Ethyltriphenylphosphonium bromideThis research focused ontriphenylphosphonium mitochondrial vector alkyl aryl modification lipophilicity. The article conveys some information:

Triphenylphosphonium (TPP+) moieties are commonly conjugated to drug mols. to confer mitochondrial selectivity due to their pos. charge and high lipophilicity. Although optimization of lipophilicity can be achieved by modifying the length of the alkyl linkers between the TPP+ moiety and the drug mol., it is not always possible. While methylation of the TPP+ moiety is a viable alternative to increase lipophilicity and mitochondrial accumulation, there are no studies comparing these two sep. modular approaches. Thus, we have systematically designed, synthesized and tested a range of TPP+ mols. with varying alkyl chain lengths and degree of aryl methylation to compare the two modular methodologies for modulating lipophilicity. The ability of aryl/alkyl modified TPP+ to deliver cargo to the mitochondria was also evaluated by confocal imaging with a TPP+-conjugated fluorescein-based fluorophore. Furthermore, we have employed mol. dynamics simulations to understand the translocation of these mols. through biol. membrane model systems. These results provide further insights into the thermodn. of this process and the effect of alkyl and aryl modular modifications. In the part of experimental materials, we found many familiar compounds, such as Ethyltriphenylphosphonium bromide(cas: 1530-32-1Application In Synthesis of Ethyltriphenylphosphonium bromide)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. CatOnium ETPB is also used as catalysts in the synthesis of certain organic compounds.Application In Synthesis of Ethyltriphenylphosphonium bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Fully renewable limonene-derived polycarbonate as a high-performance alkyd resin》 was published in Polymer International in 2020. These research results belong to Li, Chunliang; Veldhuis, Theo; Reuvers, Bart; Sablong, Rafael J.; Koning, Cor E.. Product Details of 1530-32-1 The article mentions the following:

Limonene-derived polycarbonate-based alkyd resins (ARs) have been prepared by copolymerization of limonene dioxide with CO2, catalyzed by a β-diiminate zinc-bis(trimethylsilyl)amido complex, and subsequent chem. modification with soybean oil fatty acids using triphenylethylphosphonium bromide as the catalyst. This quant. partial modification was realized via epoxy-carboxylic acid chem., affording ARs with higher oil lengths, lower polydispersities and higher glass transition temperatures (Tg) in comparison to a conventional polyester AR based on phthalic acid, multifunctional polyol pentaerythritol and soybean fatty acid. The novel limonene polycarbonate AR and the conventional polyester AR were evaluated as coatings and both the phys. drying (without the presence of the oxidative drying accelerator Borchi Oxy Coat) and chem. curing (with Borchi Oxy Coat) processes of these coatings were monitored by measuring the Koenig hardness and complex modulus development with time. A better performance was obtained for the alkyd paint containing polycarbonates modified with fatty acids (FA-PCs), which showed a faster chem. drying, a higher Koenig hardness and a higher Tg in coating evaluation, demonstrating that the fully renewable FA-PCs are promising resins for alkyd paint applications. The experimental process involved the reaction of Ethyltriphenylphosphonium bromide(cas: 1530-32-1Product Details of 1530-32-1)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.Product Details of 1530-32-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Jiang, Xiaoli; Han, Bo; Xue, Yuhang; Duan, Mei; Gui, Zhuofan; Wang, You; Zhu, Shaolin published their research in Nature Communications in 2021. The article was titled 《Nickel-catalysed migratory hydroalkynylation and enantioselective hydroalkynylation of olefins with bromoalkynes》.Related Products of 1530-32-1 The article contains the following contents:

Here, an NiH-catalyzed reductive migratory hydroalkynation of olefins such as, 4-phenyl-1-butene, (E)-1,2-diphenylethene, 1H-indene, etc. with bromoalkynes RCCBr [R = tris(propan-2-yl)silyl, triphenylmethyl, tert-butyldiphenylsilyl] that delivers the corresponding benzylic alkynation products ArCH(CH2R1)CCR [Ar = Ph, naphthalen-2-yl, thiophen-3-yl, etc.; R1 = H, Et, 2-cyclohexylethyl, Ph, etc.] in high yields with excellent regioselectivities was reported. Catalytic enantioselective hydroalkynation of styrenes (E/Z)-Ar1CH=CHR2 [Ar1 = Ph, 2-methoxyphenyl, thiophen-3-yl, etc.; R2 = H, Me, Et, Ph, etc.] has also been realized using a simple chiral PyrOx ligand. The obtained enantioenriched benzylic alkynes (S)-Ar1CH(CH2R2)CCR [R = tris(propan-2-yl)silyl, triethylsilyl, tert-butyldimethylsilyl, etc.] are versatile synthetic intermediates and can be readily transformed into synthetically useful chiral synthons. In the experiment, the researchers used Ethyltriphenylphosphonium bromide(cas: 1530-32-1Related Products of 1530-32-1)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.Related Products of 1530-32-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Ma, Tao; Hua, Jiawei; Bian, Mixue; Qin, Hong; Lin, Xinxin; Yang, Xiaobing; Liu, Chengkou; Yang, Zhao; Fang, Zheng; Guo, Kai published an article in 2022. The article was titled 《Visible light-promoted aerobic oxidative cleavage and cyclization of olefins to access 3-hydroxy-isoindolinones》, and you may find the article in Organic Chemistry Frontiers.Quality Control of Ethyltriphenylphosphonium bromide The information in the text is summarized as follows:

A convenient and environmentally friendly synthetic route from 2-vinylbenzimides to 3-hydroxy-isoindolinones through visible light-promoted transformations via iron/disulfide catalysis and mol. oxygen oxidation was developed. A range of 3-hydroxy-isoindolinones were obtained in moderate to good yields, which exhibited excellent functional group compatibility and broad substrate scope. Further mechanistic investigations proved that dioxetane might be a key intermediate being involved in the reaction. After reading the article, we found that the author used Ethyltriphenylphosphonium bromide(cas: 1530-32-1Quality Control of Ethyltriphenylphosphonium bromide)

Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.Quality Control of Ethyltriphenylphosphonium bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary