Category: 13465-09-3

In 2022,Majidi, Leily; Ahmadiparidari, Alireza; Shan, Nannan; Kumar Singh, Sachin; Zhang, Chengji; Huang, Zhehao; Rastegar, Sina; Kumar, Khagesh; Hemmat, Zahra; Ngo, Anh T.; Zapol, Peter; Cabana, Jordi; Subramanian, Arunkumar; Curtiss, Larry A.; Salehi-Khojin, Amin published an article in Small. The title of the article was 《Nanostructured Conductive Metal Organic Frameworks for Sustainable Low Charge Overpotentials in Li-Air Batteries》.Application of 13465-09-3 The author mentioned the following in the article:

Lithium-oxygen batteries are among the most attractive alternatives for future electrified transportation. However, their practical application is hindered by many obstacles. Due to the insulating nature of Li2O2 product and the slow kinetics of reactions, attaining sustainable low charge overpotentials at high rates becomes a challenge resulting in the battery′s early failure and low round trip efficiency. Herein, outstanding characteristics are discovered of a conductive metal organic framework (c-MOF) that promotes the growth of nanocrystalline Li2O2 with amorphous regions. This provides a platform for the continuous growth of Li2O2 units away from framework, enabling a fast discharge at high current rates. Moreover, the Li2O2 structure works in synergy with the redox mediator (RM). The conductivity of the amorphous regions of the Li2O2 allows the RM to act directly on the Li2O2 surface instead of catalyst edges and then transport through the electrolyte to the Li2O2 surface. This direct charge transfer enables a small charge potential of <3.7 V under high current densities (1-2 A g-1) sustained for a long cycle life (100-300 cycles) for large capacities (1000-2000 mAh g-1). These results open a new direction for utilizing c-MOFs towards advanced energy storage systems. In addition to this study using Indium(III) bromide, there are many other studies that have used Indium(III) bromide(cas: 13465-09-3Application of 13465-09-3) was used in this study.

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Application of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Jaradat, Ahmad; Zhang, Chengji; Singh, Sachin Kumar; Ahmed, Junaid; Ahmadiparidari, Alireza; Majidi, Leily; Rastegar, Sina; Hemmat, Zahra; Wang, Shuxi; Ngo, Anh T.; Curtiss, Larry A.; Daly, Matthew; Subramanian, Arunkumar; Salehi-khojin, Amin published an article in 2021. The article was titled 《High Performance Air Breathing Flexible Lithium-Air Battery》, and you may find the article in Small.Quality Control of Indium(III) bromide The information in the text is summarized as follows:

Lithium-oxygen (Li-O2) batteries possess the highest theor. energy d. (3500 Wh kg-1), which makes them attractive candidates for modern electronics and transportation applications. In this work, an inexpensive, flexible, and wearable Li-O2 battery based on the bifunctional redox mediator of InBr3, MoS2 cathode catalyst, and Fomblin-based oxygen permeable membrane that enable long-cycle-life operation of the battery in pure oxygen, dry air, and ambient air is designed, fabricated, and tested. The battery operates in ambient air with an open system air-breathing architecture and exhibits excellent cycling up to 240 at the high c.d. of 1 A g-1 with a relative humidity of 75%. The electrochem. performance of the battery including deep-discharge capacity, and rate capability remains almost identical after 1000 cycle in a bending fatigue test. This finding opens a new direction for utilizing high performance Li-O2 batteries for applications in the field of flexible and wearable electronics. The results came from multiple reactions, including the reaction of Indium(III) bromide(cas: 13465-09-3Quality Control of Indium(III) bromide)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Quality Control of Indium(III) bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2022,Yang, Hui; Xing, Baoyan; Zhao, Jianguo; Ma, Guibin published an article in Polyhedron. The title of the article was 《Methoxyl-substituted phosphine ligand properties and a case study of formation adducts to indium(III) bromide by DFT calculations》.Formula: Br3In The author mentioned the following in the article:

Six bulky triphenylphosphine ligands containing substituted methoxyl groups (tris(2,4,6-trimethoxyphenyl)phosphine (TMP), tris(2,6-dimethoxyphenyl)phosphine (TDP), tris(o-methoxyphenyl)phosphine (o-Anis3P), tris(p-methoxyphenyl)phosphine (p-Anis3P), tris(m-methoxyphenyl)phosphine (m-Anis3P) and triphenylphosphine (PPh3)) were studied by DFT (d. functional theory) calculations and exptl. solution/solid-state 31P NMR spectroscopy. The basicity and binding ability of these substituted ligands, proven by comparison of structural data with DFT-predicted data, are in the order TMP > TDP > o-Anis3P > p-Anis3P > m-Anis3P > PPh3. Mol. structures for InBr3 with bulky ligands (TMP, TDP, o-Anis3P, p-Anis3P, m-Anis3P and PPh3) were calculated using DFT. P-In bond distances generated from these six optimized mol. structures and the calculated intramol. interaction energies are in agreement with the ligand properties, with strong donation ability for those with the short bond distance; the In-P bond distance from shortest to longest follows a similar trend as predicted by DFT calculations DFT calculations for these adducts show that methoxyl substitution to triphenylphosphine (PPh3) ligands contributed to its electron donor ability resulting in lower P-In bond distances with relatively large bond interaction energies. In the part of experimental materials, we found many familiar compounds, such as Indium(III) bromide(cas: 13465-09-3Formula: Br3In)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Formula: Br3In

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

The author of 《Synthesis and structures of bis(iminophosphorano)methanide chelate complexes with zinc and group 13》 were Zhang, Jin; Ge, Sai; Zhao, Jianguo; Ulhaq, Imran; Ferguson, Michael J.; McDonald, Robert; Ma, Guibin; Cavell, Ronald G.. And the article was published in Polyhedron in 2019. Category: bromides-buliding-blocks The author mentioned the following in the article:

The organolithium bis(iminophosphorano)methandiide dimer [Li2C(Ph2P=NSiMe3)2]2 ([Li2-1]2) reacts with 4 equiv of AlCl3 in THF to generate the novel bimetallic Al carbene complex of [Li(THF)4][{C(Ph2P=NSiMe3)2}Al2Cl5] (1). Several new bis(iminophosphorano)methanide chelate-coordinated complexes of [{CH(Ph2P=NSiMe3)2}AlCl2] (2), [{CH(Ph2P=NSiMe3)2}GaBr2] (3), [{CH(Ph2P=NSiMe3)2}InCl2] (4), and [{CH(Ph2P=NSiMe3)2}InBr2] (5) were synthesized in situ while organolithium bis(iminophosphorano)methandiide ([Li2-1]2) reacts with 2 equiv of metal halides AlCl3, GaBr3 InCl3 and InBr3 resp. in THF. Also, an unexpected complex of [{CH2(Ph2P=NSiMe3)2}ZnCl2] (6) is formed as [Li2-1]2 dimer reacted with 2 equiv of ZnCl2 in situ. All six synthesized complexes (1-6) were isolated in the solid state and were structurally characterized by x-ray diffraction. Complexes containing particular carbene to metal or ionic linking interaction bonds (1-4) were selected and further characterized in detail by DFT calculations using Gaussian03 program. The DFT calculation demonstrates the existence of a carbene-Al σ bond in structure 1 and ionic linkage interaction in structures 2-4. In the experiment, the researchers used Indium(III) bromide(cas: 13465-09-3Category: bromides-buliding-blocks)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Category: bromides-buliding-blocks

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Trivalent ion mediated abnormal growth of all-inorganic perovskite nanocrystals and their divergent emission properties》 was written by Dong, Xunyi; Acheampong Tsiwah, Emmanuel; Li, Tan; Hu, Junjie; Li, Zixiong; Ding, Yanxi; Deng, Zhao; Chen, Wenhui; Xu, Like; Gao, Peng; Zhao, Xiujian; Xie, Yi. Related Products of 13465-09-3This research focused ontrivalent ion dopped inorganic perovskite nanocrystal photoluminescence optical absorption. The article conveys some information:

In this work, a new trivalent ion-mediated one-pot synthetic protocol is reported to create two well-defined optical absorbance and photoluminescence (PL) emissions in all-inorganic halide perovskite nanocrystals (NCs). The foreign M3+ cations (M = Bi, Al, In), typically from BiBr3, BiFeO3, BiCl3, AlBr3 or InBr3, function as capping ligands for generating a growth-constrained thinner nanoplatelet (NPL) population displaying the quantum confinement effect. The formation mechanism of the growth-constrained NPLs is proposed based on d. functional theory (DFT) on the different slab energy of the representative NPLs achieved in the presence of Bi3+ ions and the d. of states (DOS) of the supposed bulk perovskites. Notably, the formation of two groups of NCs with different sizes allows for the generation of dual optical absorbance and PL emissions. The influence of the M : Pb molar ratios on the precursors is systematically elucidated, from which the relative intensity and position of each PL emission can be fine-tuned. By virtue of the representative NPLs with well-defined green and blue emissions, the M3+-assisted synthetic protocol provides a facile and cost-effective route for producing unique NCs and nanostructures for optoelectronic device applications. After reading the article, we found that the author used Indium(III) bromide(cas: 13465-09-3Related Products of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Related Products of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Formula: Br3InIn 2020 ,《In Situ Transmission Electron Microscopy Measurements of Ge Nanowire Synthesis with Liquid Metal Nanodroplets in Water》 was published in ACS Nano. The article was written by Cheek, Quintin; Fahrenkrug, Eli; Hlynchuk, Sofiya; Alsem, Daan Hein; Salmon, Norman J.; Maldonado, Stephen. The article contains the following contents:

The growth of Ge nanowires in water inside a liquid transmission electron microscope (TEM) holder has been demonstrated at room temperature Each nanowire growth event was stimulated by the incident electron beam on otherwise unsupported liquid Ga or liquid In nanodroplets. A variety of conditions were explored, including liquid metal nanodroplet surface condition, liquid metal nanodroplet size and d., formal concentration of dissolved GeO2, and electron beam intensity. The cumulative observations from a series of videos recorded during growth events suggested the following points. First, the conditions necessary for initiating nanowire growth at uncontacted liquid metal nanodroplets in a liquid TEM cell indicate the process was governed by solvated electrons generated from secondary electrons scattered by the liquid metal nanodroplets. The attained current densities were comparable to those achieved in conventional electrochem. liquid-liquid-solid (ec-LLS) growths outside of a TEM. Second, the surface condition of the liquid metal nanodroplets was quite influential on whether nanowire growth occurred and surface diffusion of Ge adatoms contributed to the rate of crystallization Third, the Ge nanowire growth rates were limited by the feed rate of Ge to the crystal growth front rather than the rate of crystallization at the liquid metal/solid Ge interface. Estimates of an electrochem. current for the reduction of dissolved GeO2 were nominally in line with currents used for Ge nanowire growth by ec-LLS outside of the TEM. Fourth, the Ge nanowire growths in the liquid TEM cell occurred far from thermodn. equilibrium, with supersaturation values of 104 prior to nucleation. These collective points provide insight on how to further control and improve Ge nanowire morphol. and crystallog. quality by the ec-LLS method.Indium(III) bromide(cas: 13465-09-3Formula: Br3In) was used in this study.

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Formula: Br3In

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2022,Zhang, Wenqi; Lin, Zhichao; Cai, Qingbin; Xu, Xiangning; Dong, Hongye; Mu, Cheng; Zhang, Jian-Ping published an article in ChemSusChem. The title of the article was 《Electron Transport Assisted by Transparent Conductive Oxide Elements in Perovskite Solar Cells》.Product Details of 13465-09-3 The author mentioned the following in the article:

Fluorine and indium elements in Fluorine doped tin oxide and tin doped Indium oxide, resp., significantly contribute toward enhancing the elec. conductivity of these transparent conductive oxides. In this study, fluorine was combined with indium to modify the tinoxide electron transport layer through Indiumoxide. Consequently, the modified perovskite solar cells showe the favorable alignment of energy levels, improved absorption and utilization of light, enhanced interfacial charge extraction, and suppressed interfacial charge recombination. After indium fluoride modification, the open circuit voltage and fill factor of the perovskite solar cells were significantly improved, and the photoelec. conversion efficiency reached 21.39%, far exceeding that of the control perovskite solar cells (19.62%). In the experiment, the researchers used many compounds, for example, Indium(III) bromide(cas: 13465-09-3Product Details of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Product Details of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2019,Organic Letters included an article by Zhou, Lan; Shen, Yao-Bin; An, Xiao-De; Li, Xian-Jiang; Li, Shuai-Shuai; Liu, Qing; Xiao, Jian. Application of 13465-09-3. The article was titled 《Redox-Neutral β-C(sp3)-H Functionalization of Cyclic Amines via Intermolecular Hydride Transfer》. The information in the text is summarized as follows:

The first redox-neutral and transition-metal-free β-C(sp3)-H functionalization of cyclic amines via a consecutive intermol. hydride transfer process is reported. A series of N-aryl pyrrolidines and N-aryl 1,2,3,4-tetrahydropyridines decorated with CF3 and carboxylic ester functionalities are directly accessed in good yields from pyrrolidines and piperidines. This work pushes forward the application of the intermol. hydride transfer strategy in one-step assembly of mol. complexity. The experimental process involved the reaction of Indium(III) bromide(cas: 13465-09-3Application of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Application of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Chi, Kailin; Xu, Hansi; Feng, Bingtao; Meng, Xianwei; Yu, Daoyu; Li, Qian published their research in Nanomaterials in 2021. The article was titled 《Controlled Growth of Porous InBr3: PbBr2 Film for Preparation of CsPbBr3 in Carbon-Based Planar Perovskite Solar Cells》.Computed Properties of Br3In The article contains the following contents:

Due to the low solubility of CsBr in organic solvents, the CsPbBr3 film prepared by the multi-step method has holes and insufficient thickness, and the light absorption capacity and c.d. of the perovskite film hinder the further improvement in the power conversion efficiency (PCE) of CsPbBr3 solar cells. In this study, we introduced InBr3 into the PbBr2 precursor solution and adjusted the concentration of PbBr2, successfully prepared PbBr2 with a porous structure on the compact TiO2 (c-TiO2) substrate to ensure that it fully reacted with CsBr, and obtained the planar carbon-based CsPbBr3 solar cells with high-quality perovskite film. The results reveal that the porous PbBr2 structure and the increasing PbBr2 concentration are beneficial to increase the thickness of the CsPbBr3 films, optimize the surface morphol., and significantly enhance the light absorption capacity. Finally, the PCE of the CsPbBr3 solar cells obtained after conditions optimization was 5.76%.Indium(III) bromide(cas: 13465-09-3Computed Properties of Br3In) was used in this study.

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Computed Properties of Br3In

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Safety of Indium(III) bromideIn 2019 ,《Cobalt-Catalyzed Hydroacylative Dimerization of Allenes Leading to Skipped Dienes》 was published in Organic Letters. The article was written by Ding, Wei; Ho, Yan King Terence; Okuda, Yasuhiro; Wijaya, Christopher Kevin; Tan, Zheng Hao; Yoshikai, Naohiko. The article contains the following contents:

A cobalt-diphosphine catalyst was found to promote a selective 1:2 coupling reaction between aldehydes and allenes to form β,δ-dialkylidene ketones, featuring skipped diene moieties, with high regioselectivities and stereoselectivities. The reaction is distinct from previously reported, rhodium-catalyzed aldehyde-allene 1:2 coupling to afford β,γ-dialkylidene ketones bearing 1,3-diene moieties. The present hydroacylative dimerization involves a unique allene/allene oxidative cyclization mode to form a C1-C2 linkage between the allene mols. The experimental part of the paper was very detailed, including the reaction process of Indium(III) bromide(cas: 13465-09-3Safety of Indium(III) bromide)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Safety of Indium(III) bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary