Bonnefoy, Clemence et al. published their research in Chemistry – A European Journal in 2021 |CAS: 2567-29-5

The Article related to fluoromethoxylative substitution nitrotrifluoromethoxybenzene, 2,4-dinitro-trifluoromethoxybenzene, fluorine, nucleophilic substitution, trifluoromethoxide anion, trifluoromethoxylation and other aspects.Synthetic Route of 2567-29-5

On November 17, 2021, Bonnefoy, Clemence; Chefdeville, Emmanuel; Panosian, Armen; Hanquet, Gilles; Leroux, Frederic R.; Toulgoat, Fabien; Billard, Thierry published an article.Synthetic Route of 2567-29-5 The title of the article was Study of a Stable “Trifluoromethoxide Anion Solution” Arising from 2,4-Dinitro-Trifluoromethoxybenzene. And the article contained the following:

Despite recent advances, trifluoromethoxylation remains a challenging reaction. Here we describe an efficient trifluoromethoxylative substitution, using an inexpensive and easy-to-handle reagent. By mixing DMAP with a slight excess of 2,4-dinitro-trifluoromethoxybenzene (DNTFB), a stable solution of trifluoromethoxide anion is obtained and can be used to perform a SN2 reaction without any silver additives. A precise study of the properties and behavior of this unusual stable solution of CF3O- species is also performed. The experimental process involved the reaction of 4-(Bromomethyl)-1,1′-biphenyl(cas: 2567-29-5).Synthetic Route of 2567-29-5

The Article related to fluoromethoxylative substitution nitrotrifluoromethoxybenzene, 2,4-dinitro-trifluoromethoxybenzene, fluorine, nucleophilic substitution, trifluoromethoxide anion, trifluoromethoxylation and other aspects.Synthetic Route of 2567-29-5

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary