In 2022,Yuan, Wei; Zhu, Xujiang; Xu, Yankun; He, Chuan published an article in Angewandte Chemie, International Edition. The title of the article was 《Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation》.Recommanded Product: 1-Bromo-2-isopropylbenzene The author mentioned the following in the article:
Despite growing progress in the construction of chiral organosilicon compounds, the catalytic asym. synthesis of silicon-stereogenic silanols is less explored and remains a considerable challenge. Herein, authors report the first enantioselective construction of silicon-stereogenic silanols by the catalytic asym. hydrolytic oxidation of dihydrosilanes. This practical procedure features ambient reaction conditions, high atom economy, good functional-group compatibility, and H2 as the only byproduct, and produces a wide range of valuable chiral silanols and bis-silanols in decent yields with excellent chemo- and stereoselectivity.1-Bromo-2-isopropylbenzene(cas: 7073-94-1Recommanded Product: 1-Bromo-2-isopropylbenzene) was used in this study.
1-Bromo-2-isopropylbenzene(cas: 7073-94-1) belongs to organobromine compounds.Most of the natural organobromine compounds are produced by marine organisms , and several brominated metabolites with antibacterial , antitumor , antiviral , and antifungal activity have been isolated from seaweed, sponges, corals, molluscs, and others. In contrast, terrestrial plants account only for a few bromine-containing compounds.Recommanded Product: 1-Bromo-2-isopropylbenzene
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary