Synthetic Route of C7H13BrO2In 2021 ,《Hydrazone exchange: a viable route for the solid-tethered synthesis of [2]rotaxanes》 was published in New Journal of Chemistry. The article was written by Da Silva Rodrigues, Rafael; Luis, Ena T.; Marshall, David L.; McMurtrie, John C.; Mullen, Kathleen M.. The article contains the following contents:
Building on the success of other dynamic covalent synthetic methods, hydrazone exchange as a strategy to improve the formation of rotaxanes in solution and on solid surfaces were presented. Solution-state analogs containing naphthalenediimide (NDI) or bipyridinium motifs and 1,5-dinaphtho[38]crown-10 were initially prepared to establish ideal conditions for maintaining thermal equilibrium throughout the exchange reaction. Solid-state rotaxanes were synthesized on hydrazide-functionalised TentaGel polymer resins and analyzed with HR MAS 1H NMR spectroscopy. Surface rotaxane functionalisation of 80% was achieved for the NDI rotaxane, which was significantly higher than previously reported with either dynamic covalent or traditional irreversible synthetic strategies.Ethyl 5-bromovalerate(cas: 14660-52-7Synthetic Route of C7H13BrO2) was used in this study.
Ethyl 5-bromovalerate(cas: 14660-52-7) belongs to bromides. One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine.Synthetic Route of C7H13BrO2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary