Caspers, Lucien D.; Spils, Julian; Damrath, Mattis; Lork, Enno; Nachtsheim, Boris J. published the artcile< One-Pot Synthesis and Conformational Analysis of Six-Membered Cyclic Iodonium Salts>, Product Details of C7H6BrNO2, the main research area is iodobenzyl alc Friedel Crafts oxidation cyclization one pot conformation; diaryliodonium salt preparation.
Two one-pot procedures for the construction of carbon-bridged diaryliodonium triflates and tetrafluoroborates, e.g., I, are described. Strong Bronsted acids enable the effective Friedel-Crafts alkylation with diversely substituted o-iodobenzyl alc. derivatives, providing diphenylmethane scaffolds, which are subsequently oxidized and cyclized to the corresponding dibenzo[b,e]iodininium salts. Based on NMR investigations and d. functional theory (DFT) calculations, we could verify the so-far-undescribed existence of two stable isomers in cyclic iodonium salts substituted with aliphatic side chains in the carbon bridge.
Journal of Organic Chemistry published new progress about Aralkyl alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (o-iodo). 20776-50-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H6BrNO2, Product Details of C7H6BrNO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary