Kubota, Koji; Endo, Tsubura; Uesugi, Minami; Hayashi, Yuta; Ito, Hajime published the artcile< Solid-State C-N Cross-Coupling Reactions with Carbazoles as Nitrogen Nucleophiles Using Mechanochemistry>, Product Details of C8H5BrS2, the main research area is arylcarbazole preparation; aryl halide arylcarbazole solid state cross coupling palladium catalyst; ball milling; carbazole; cross-coupling; mechanochemistry; solid-state reaction.
The palladium-catalyzed solid-state C-N cross-coupling of carbazoles with aryl halides via a high-temperature ball-milling technique was reported. This reaction allowed simple, fast, and efficient synthesis of N-arylcarbazole derivatives I [R1 = 4-MePh, 2-naphthyl, 9-pyrenyl, etc.; R2 = H, t-Bu, Ph, etc.] in good to excellent yields without the use of large amounts of organic solvents in air. Importantly, the developed solid-state coupling approach enabled the cross-coupling of poorly soluble aryl halides with large polyaromatic structures that are barely reactive under conventional solution-based conditions.
ChemSusChem published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 3480-11-3 belongs to class bromides-buliding-blocks, and the molecular formula is C8H5BrS2, Product Details of C8H5BrS2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary