Sun, Ningwei; Su, Kaixin; Zhou, Ziwei; Wang, Daming; Fery, Andreas; Lissel, Franziska; Zhao, Xiaogang; Chen, Chunhai published the artcile< ""Colorless-to-Black"" electrochromic and AIE-active polyamides: an effective strategy for the highest-contrast electrofluorochromism>, Application In Synthesis of 184239-35-8, the main research area is Colorless Black electrochromic AIE active polyamides effective strategy.
Electrofluorochromic (EFC) materials have gained extensive attention owing to their interesting modulations of fluorescence by an elec. stimulus. However, the limited performances, especially the low fluorescence on/off contrast, significantly hampered their further applications. Herein, we design a new strategy to achieve high-contrast electrofluorochromism by combinations of “”colorless-to-black”” electrochromism and highly fluorescent AIE activity. Given the effective fluorescence quenching effect and high solid-state fluorescence, a fluorescence contrast of 838 is realized, to the best of our knowledge, the highest reported so far. Furthermore, to explore the structure-property relationships, we also separated the E/Z isomers of tetraphenylethylene (TPE) and studied the properties of the three electroactive/fluorescent polymers (11TPE-PA, E-12TPE-PA, and Z-12TPE-PA) derived from different TPE derivatives and isomers. The three branches of polymers all exhibited AIE-active and “”colorless-to-black”” electrochromic (EC) properties. In addition to the ultrahigh fluorescence contrast, Z-12TPE-PA also integrated high electrochromic contrast (Δ% T = 92%), short response time (0.6 s/0.3 s), and excellent switching stability (300 cycles), paving the way for the applications in various electronic applications. The study will provide novel insights into the future design and development of high-performance EC/EFC materials.
Macromolecules (Washington, DC, United States) published new progress about Electrochromic materials. 184239-35-8 belongs to class bromides-buliding-blocks, and the molecular formula is C26H18Br2, Application In Synthesis of 184239-35-8.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary