Nazarahari, Maryam’s team published research in Chemical Papers in 2021-11-30 | 3959-07-7

Chemical Papers published new progress about Aralkyl amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Product Details of C7H8BrN.

Nazarahari, Maryam; Azizian, Javad published the artcile< FeCl2-PPh3 as an efficient catalytic system for the acceptorless dehydrogenation of amines into imines>, Product Details of C7H8BrN, the main research area is benzylamine iron chloride triphenylphosphine catalyst diastereoselective dehydrogenative coupling; phenylmethanimine preparation.

A novel and simple catalytic system including FeCl2, PPh3 and potassium tert-butoxide were employed for the synthesis of imines from amines. In order to prove the catalytic acceptorless dehydrogenation pathway for this transformation, the liberated H2 gas was detected by NMR spectroscopy. By utilizing this protocol, a variety of arylamines were used successfully for the preparation of corresponding imines in good to excellent yields (on a 1 mmol scale, 73-91% yield for homocoupling, 71 and 91% for heterocoupling).

Chemical Papers published new progress about Aralkyl amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Product Details of C7H8BrN.

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary