Wu, Wei; Wang, Biyun; Ji, Xinfei; Cao, Song published the artcile< Direct copper-catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with AgSCF3>, Application of C7H4BrF3S, the main research area is arylboronic acid silver trifluoromethylthiolate copper catalyst trifluoromethylthiolation; aryl trifluoromethyl thioether preparation.
A copper-catalyzed direct oxidative trifluoromethylthiolation of aryl boronic acids with AgSCF3 was developed. This approach provided straightforward and efficient access to a variety of aryl trifluoromethyl sulfides from an easily prepared and stable nucleophilic trifluoromethylthiolation reagent AgSCF3, and readily available nucleophilic arylboronic acids, thus avoiding the preparation of electrophilic trifluoromethylthiolating reagents in advance. Preliminary mechanistic experiments indicated that AgSCF3 served as both a source of SCF3 and an oxidant.
Organic Chemistry Frontiers published new progress about Arylboronic acids Role: RCT (Reactant), RACT (Reactant or Reagent). 2252-45-1 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3S, Application of C7H4BrF3S.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary