Hung, Vu Thai; Tran, Cong Chi; Yamamoto, Yuki; Kodama, Shintaro; Nomoto, Akihiro; Ogawa, Akiya published the artcile< Clarification on the Reactivity of Diaryl Diselenides toward Hexacyclohexyldilead under Light>, HPLC of Formula: 401-78-5, the main research area is aryl cyclohexyl selenide preparation; diaryl diselenide hexacyclohexyldilead light irradation; diaryl dichalcogenides; hexacyclohexyldilead; homolytic substitution; photoirradiation.
In this study, the reactivity of organochalcogen compounds toward a representative alkyl-lead bond compound under light was investigated in detail. Under light irradiation, the Cy-Pb bond of Cy6Pb2 (Cy = cyclohexyl) undergoes homolytic cleavage to generate a cyclohexyl radical (Cy·). This radical can be successfully captured by di-Ph diselenide, which exhibits excellent carbon-radical-capturing ability. In the case of (PhS)2 and (PhTe)2, the yields of the corresponding cyclohexyl sulfides and tellurides were lower than that of (PhSe)2. This probably occurred due to the low carbon-radical-capturing ability of (PhS)2 and the high photosensitivity of the cyclohexyl-tellurium bond.
Molecules published new progress about Diselenides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 401-78-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3, HPLC of Formula: 401-78-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary