Peng, Pan; Yan, Xingxiu; Zhang, Ke; Liu, Zhao; Zeng, Li; Chen, Yixuan; Zhang, Heng; Lei, Aiwen published the artcile< Electrochemical C-C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules>, Application of C7H7BrO2S, the main research area is aryl fluoropropane regioselective chemoselective preparation; aromatic cyclopropane triethylamine trihydrofluoride electrochem bond cleavage fluorination; alc aryl cyclopropane electrochem bond cleavage oxyfluorination; ether aryl cyclopropane electrochem bond cleavage oxyfluorination; methanol aryl cyclopropane electrochem bond cleavage dioxygenation.
An electrochem. C-C bond cleavage and 1,3-difuntionalization of arylcyclopropanes under catalyst-free and external-oxidant-free conditions. It involved 1,3-difluorination, 1,3-oxyfluorination and 1,3-dioxygenation of arylcyclopropanes with a high chemo- and regioselectivity by the strategic choice of nucleophiles. This protocol has good functional groups tolerance and can be scaled up. Mechanistic studies demonstrated that arylcyclopropane radical cation obtained from the anode oxidation and the subsequently generated benzyl carbonium were the key intermediates in this transformation. This development provided a scenario for constructing 1,3-difunctionalized mols.
Nature Communications published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 5751-83-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H7BrO2S, Application of C7H7BrO2S.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary