Rahaman, S. M. Wahidur; Pandey, Dilip K.; Rivada-Wheelaghan, Orestes; Dubey, Abhishek; Fayzullin, Robert R.; Khusnutdinova, Julia R. published the artcile< Hydrogenation of Alkenes Catalyzed by a Non-pincer Mn Complex>, Related Products of 2725-82-8, the main research area is alkane preparation; alkene hydrogenation manganese catalyst.
Hydrogenation of substituted styrenes and unactivated aliphatic alkenes by mol. hydrogen has been achieved using a Mn catalyst with a non-pincer, picolylphosphine ligand. This is the second reported example of alkene hydrogenation catalyzed by a Mn complex. Mechanistic studies showed that a Mn hydride formed by H2 activation in the presence of a base is the catalytically active species. Based on exptl. and DFT studies, H2 splitting is proposed to occur via a metal-ligand cooperative pathway involving deprotonation of the CH2 arm of the ligand, leading to pyridine dearomatization.
ChemCatChem published new progress about Alkanes Role: SPN (Synthetic Preparation), PREP (Preparation). 2725-82-8 belongs to class bromides-buliding-blocks, and the molecular formula is C8H9Br, Related Products of 2725-82-8.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary