Yamano, Ryota; Hara, Jun; Murayama, Koichi; Sugiyama, Haruki; Teraoka, Kota; Uekusa, Hidehiro; Kawauchi, Susumu; Shibata, Yu; Tanaka, Ken published the artcile< Rh-Mediated Enantioselective Synthesis, Crystal Structures, and Photophysical/Chiroptical Properties of Phenanthrenol-Based [9]Helicene-like Molecules>, Application of C7H7BrO2, the main research area is enantioselective synthesis phenanthrenol based nonahelicene.
The enantioselective synthesis of phenanthrenol-based [9]helicene-like mols. has been achieved via the rhodium-mediated intramol. [2+2+2] cycloadditions of 3-phenanthrenol-linked triynes. Crystal structures and photophys./chiroptical properties of these [9]helicene-like mols. were compared with the corresponding [7]helicene-like mols.
Organic Letters published new progress about [2+2+2] Cycloaddition reaction. 135999-16-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H7BrO2, Application of C7H7BrO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary