Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides. 585-76-2, formula is C7H5BrO2, Name is 3-Bromobenzoic acid. Organic compounds having carbon bonded to bromine are called organic bromides. Related Products of 585-76-2.
Brager, Dominique M.;Marwitz, Alexander C.;Cahill, Christopher L. research published 《 A spectroscopic, structural, and computational study of Ag-oxo interactions in Ag+/UO22+ complexes》, the research content is summarized as follows. Twelve novel Ag+/UO22+ heterometallic complexes have been prepared and characterized via structural, spectroscopic, and computational methods to probe the effects of Ag-oxo interactions on bonding and photophys. properties of the uranyl cation. Structural characterization reveals Ag-oxo interaction distances ranging from 2.475(3) Å to 4.287(4) Å. These interactions were probed using luminescence and Raman spectroscopy which displayed little effect on the luminescence intensity and the energy of the Raman active U=O sym. stretch peak as compared to previously reported Pb-oxo interactions. Computational efforts via d. functional theory-based natural bond orbital anal. revealed that the highest stabilization energy associated with the Ag-oxo interaction had a value of only 11.03 kcal mol-1 and that all other energy values fell at 7.05 kcal mol-1 or below indicating weaker interactions relative to those previously reported for Pb2+/UO22+ heterometallic compounds In contrast, quantum theory of atoms in mols. anal. of bond critical point electron d. values indicated higher electron d. in Ag-oxo interactions as compared to Pb-oxo interactions which suggests more covalent character with the Ag+. Overall, this data indicates that Ag+ has a less significant effect on UO22+ bonding and photophys. properties as compared to other Pb2+, likely due to the high polarizability of the cation.
Related Products of 585-76-2, 3-bromobenzoic acid is a bromobenzoic acid carrying a single bromo subsituent at the 3-position.
3-Bromobenzoic acid, also known as 3-Bromobenzoic acid, is a useful research compound. Its molecular formula is C7H5BrO2 and its molecular weight is 201.02 g/mol. The purity is usually 95%.
3-bromobenzoic acid is used as a reagent in the synthesis of deoxypodophyllotoxin derivatives with insecticidal activity. Also used as a reagent in the synthesis of thiazole derivatives with antibacterial activity.
3-bromobenzoic acid is a molecule that is classified as a Group P2. It has an electronegativity of 1.3 and an acidity of 0.8, which are both in the middle range of values for this group. 3-Bromobenzoic acid is soluble in water and is soluble in ethanol, acetone, and ether. The chemical structure of 3-bromobenzoic acid can be determined by its monoclonal antibody binding sites, electrochemical impedance spectroscopy data, and Langmuir adsorption isotherm data. 3-Bromobenzoic acid reacts with hydrochloric acid to form benzoate and HCl gas. Chronic exposure to 3-bromobenzoic acid has been shown to cause glutamate dehydrogenase inhibition, leading to an accumulation of p-hydroxybenzoic acid in the body. , 585-76-2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary