Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 286014-53-7, is researched, Molecular C21H25BF4N2, about Tunable Heterogeneous Catalysis: N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts To Tune Reactivity and Selectivity, the main research direction is nitrogen heterocyclic carbene ligand ruthenium heterogeneous catalysis XAFS TXRF.Application of 286014-53-7.
Here we report, for the first time, an extensive characterization of an N-heterocyclic carbene (NHC)-modified supported heterogeneous catalyst. The existence of the metal-carbene bond could be proven by 13C-SS-NMR experiments Furthermore, it could be shown that the modification with NHCs does not structurally change the catalyst itself. The effect of the nature and the loading of the NHC on the activity and selectivity of the heterogeneous catalyst is presented by a hydrogenation study, finally leading to an NHC-enabled tunable heterogeneous catalyst for chemoselective hydrogenation.
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Reference:
Bromide – Wikipedia,
bromide – Wiktionary