Carbonylation of bromo(bromomethyl)benzenes to alkyl carboalkoxyphenylacetates catalyzed by cobalt carbonyl was written by Shim, Sang Chul;Doh, Chil Hoon;Lee, Dong Yub;Youn, Young Zoo;Lee, Seung Yub;Chae, Shin Ae;Oh, Dae Hee;Oh, Hunseung. And the article was included in Bulletin of the Korean Chemical Society in 1992.Synthetic Route of C10H11BrO2 This article mentions the following:
Carbonylation of bromo(bromomethyl)benzene catalyzed by cobalt carbonyl gave (alkoxycarbonyl)phenylacetates. Carbonylation of 1-bromo-4-(bromomethyl)benzene with CO/Co2(CO)8/EtOH/MeI gave 98% Et [4-(ethoxycarbonyl)phenyl]acetate. The effects of base and alcs. in this reaction were examined In the experiment, the researchers used many compounds, for example, Ethyl (2-bromophenyl)acetate (cas: 2178-24-7Synthetic Route of C10H11BrO2).
Ethyl (2-bromophenyl)acetate (cas: 2178-24-7) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Synthetic Route of C10H11BrO2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary