Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation was written by Kliman, Laura T.;Mlynarski, Scott N.;Ferris, Grace E.;Morken, James P.. And the article was included in Angewandte Chemie, International Edition in 2012.Recommanded Product: 28322-40-9 This article mentions the following:
A catalytic enantioselective 1,2-diboration of 1,3-dienes has been described. The 1,2-bis(boronate) products can be employed in versatile stereoselective allylation reactions and deliver a range of functionalized chiral building blocks. In the experiment, the researchers used many compounds, for example, Isopentyltriphenylphosphonium bromide (cas: 28322-40-9Recommanded Product: 28322-40-9).
Isopentyltriphenylphosphonium bromide (cas: 28322-40-9) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. For many applications, organobromides represent a compromise of reactivity and cost.Recommanded Product: 28322-40-9
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary