Mechanochemical Aliphatic Iodination (and Bromination) by Cascaded Cyclization was written by Bal, Ankita;Kumar Dinda, Tarun;Mal, Prasenjit. And the article was included in Asian Journal of Organic Chemistry in 2022.Category: bromides-buliding-blocks This article mentions the following:
Herein, the synthesis of oxazoline derivatives I [Ar = Ph, 4-MeC6H4, 3-BrC6H4, etc.] from N-allyl benzamides via mechanochem. cascaded cyclization and halogenation using N-iodo- and N-bromosuccinimides, resp., as bifunctional reagents was demonstrated. In the experiment, the researchers used many compounds, for example, 1-Bromopyrrolidine-2,5-dione (cas: 128-08-5Category: bromides-buliding-blocks).
1-Bromopyrrolidine-2,5-dione (cas: 128-08-5) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. For many applications, organobromides represent a compromise of reactivity and cost.Category: bromides-buliding-blocks
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary