Lenstra, Danny C. published the artcileCatalytic Staudinger Reduction at Room Temperature, Application of (4-Bromo-2-fluorophenyl)methanamine hydrochloride, the publication is Journal of Organic Chemistry (2019), 84(10), 6536-6545, database is CAplus and MEDLINE.
We report an efficient catalytic Staudinger reduction at room temperature that enables the preparation of a structurally diverse set of amines from azides in excellent yields. The reaction is based on the use of catalytic amounts of triphenylphosphine as a phosphine source and diphenyldisiloxane as a reducing agent. Our catalytic Staudinger reduction exhibits a high chemoselectivity, as exemplified by reduction of azides over other common functionalities, including nitriles, alkenes, alkynes, esters, and ketones.
Journal of Organic Chemistry published new progress about 147181-08-6. 147181-08-6 belongs to bromides-buliding-blocks, auxiliary class Fluoride,Bromide,Salt,Amine,Benzene, name is (4-Bromo-2-fluorophenyl)methanamine hydrochloride, and the molecular formula is C7H8BrClFN, Application of (4-Bromo-2-fluorophenyl)methanamine hydrochloride.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary