Martinez, Gabriel Espinosa’s team published research in Journal of the American Chemical Society in 138 | CAS: 111865-47-5

Journal of the American Chemical Society published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, SDS of cas: 111865-47-5.

Martinez, Gabriel Espinosa published the artcileAccessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates, SDS of cas: 111865-47-5, the publication is Journal of the American Chemical Society (2016), 138(13), 4290-4293, database is CAplus and MEDLINE.

This communication describes the two-electron oxidation of (DIPPCCC)NiX (DIPPCCC = bis(diisopropylphenyl-benzimidazol-2-ylidene)phenyl; X = Cl or Br) with halogen and halogen surrogates to form (DIPPCCC)NiX3. These complexes represent a rare oxidation state of Ni, as well as an unprecedented reaction pathway to access these species through Br2 and halogen surrogate (benzyltrimethylammonium tribromide). The Ni(IV) complexes were characterized by a suite of spectroscopic techniques and can readily reduce to the Ni(II) counterpart, allowing for cycling between the Ni(II)/Ni(IV) oxidation states.

Journal of the American Chemical Society published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, SDS of cas: 111865-47-5.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary