Adam, Rosa published the artcileSelf-Assembly of Catalytically Active Supramolecular Coordination Compounds within Metal-Organic Frameworks, Category: bromides-buliding-blocks, the publication is Journal of the American Chemical Society (2019), 141(26), 10350-10360, database is CAplus and MEDLINE.
Supramol. coordination compounds (SCCs) represent the power of coordination chem. methodologies to self-assemble discrete architectures with targeted properties. SCCs are generally synthesized in solution, with isolated fully coordinated metal atoms as structural nodes, thus severely limited as metal-based catalysts. Metal-organic frameworks (MOFs) show unique features to act as chem. nanoreactors for the in situ synthesis and stabilization of otherwise not accessible functional species. Here, authors present the self-assembly of PdII SCCs within the confined space of a pre-formed MOF (SCCs@MOF) and its post-assembly metalation to give a PdII-AuIII supramol. assembly, crystallog. underpinned. These SCCs@MOFs catalyze the coupling of boronic acids and/or alkynes, representative multi-site metal-catalyzed reactions in which traditional SCCs tend to decompose, and retain their structural integrity as a consequence of the synergetic hybridization between SCCs and MOFs. These results open new avenues in both the synthesis of novel SCCs and their use in heterogeneous metal-based supramol. catalysis.
Journal of the American Chemical Society published new progress about 16523-02-7. 16523-02-7 belongs to bromides-buliding-blocks, auxiliary class Bromide,Sulfone,Aliphatic hydrocarbon chain, name is 2-Bromoethyl Methyl Sulfone, and the molecular formula is C3H7BrO2S, Category: bromides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary