Raphael Karikachery, Alice’s team published research in Inorganic Chemistry in 52 | CAS: 594-81-0

Inorganic Chemistry published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H12Br2, Recommanded Product: 2,3-Dibromo-2,3-dimethylbutane.

Raphael Karikachery, Alice published the artcileHigh Quantum Yield Molecular Bromine Photoelimination from Mononuclear Platinum(IV) Complexes, Recommanded Product: 2,3-Dibromo-2,3-dimethylbutane, the publication is Inorganic Chemistry (2013), 52(7), 4113-4119, database is CAplus and MEDLINE.

Pt(IV) complexes trans-Pt(PEt3)2(R)(Br)3 (R = Br, aryl and polycyclic aromatic fragments) photoeliminate mol. bromine with quantum yields as high as 82%. Photoelimination occurs both in the solid state and in solution Calorimetry measurements and DFT calculations (PMe3 analogs) indicate endothermic and endergonic photoeliminations with free energies from 2 to 22 kcal/mol of Br2. Solution trapping experiments with high concentrations of 2,3-dimethyl-2-butene suggest a radical-like excited state precursor to bromine elimination.

Inorganic Chemistry published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H12Br2, Recommanded Product: 2,3-Dibromo-2,3-dimethylbutane.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary