Dickner, Tim published the artcileStereoselective synthesis and binding properties of novel concave-shaped indolizino[3,4-b]quinolines, Product Details of C7H13BrSi, the publication is Journal fuer Praktische Chemie (Weinheim, Germany) (2000), 342(8), 804-811, database is CAplus.
Novel all-cis-configurated indolizino[3,4-b]quinoline receptors I [R = Me, R1 = H, Ph(CH2)3O; R2 = H, PhNHCO] were prepared via diastereoselective Lewis acid-catalyzed cyclization of N-arylimines II as a key step. In order to obtain the indolizino[3,4-b]quinoline I (R = R2 = H; R1 = Cl), an N-arylimine precursor II (III; R = Me3Si; R1 = Cl; R2 = H) was prepared in 8 steps from L-prolinol. In contrast to the known β-effect of silyl groups, cyclization of III proceeded via α-carbenium ion species to give the diastereomeric products I (R = Me3Si; R1 = Cl; R2 = H), which were desilylated to I (R = R2 = H; R1 = Cl). The association constants for receptors I decreased in the order I (R = R2 = H; R1 = Cl) > I (R = Me; R1 = R2 = H) > I (R= Me; R1 = H; R2 = PhNHCO) > I [R = Me; R1 = Ph(CH2)3O; R2 = H] for both acetic acid and N-Z-phenylalanine as substrates.
Journal fuer Praktische Chemie (Weinheim, Germany) published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, Product Details of C7H13BrSi.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary