Dey, Madhudeepa published the artcileNovel method of synthesis of quaternary ammonium tribromides and investigation of catalytic role of benzyltrimethylammonium tribromide in oxidation of alcohols to carbonyl compounds, Application In Synthesis of 111865-47-5, the publication is Synthetic Communications (2013), 43(12), 1734-1742, database is CAplus.
Stable crystalline organic quaternary ammonium tribromides (QATBs) were easily synthesized by the oxidation of the corresponding organic ammonium bromides (QABs) with ammonium persulfate. The reactions were performed under solvent-free conditions in presence of sulfuric acid and silica as supporting agent. Two equivalents of potassium bromide were used as the source of addnl. bromides for quant. conversion of QABs to QATBs. Ammonium persulfate, a cheap and readily available oxidant carries out the bromide oxidation to tribromide very effectively under solvent-free conditions. The synthesized QATBs catalyzed the oxidation of alcs. to carbonyl compounds with hydrogen peroxide as oxidant in high yields under mild reaction conditions.
Synthetic Communications published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Application In Synthesis of 111865-47-5.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary