Teichmann, Marcus’s team published research in Synthesis in | CAS: 111865-47-5

Synthesis published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C6H12N2O, Application of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide.

Teichmann, Marcus published the artcileBromination of 1,5-anhydrohex-1-enitols (glycals) using quaternary ammonium tribromides as bromine donors: synthesis of α-1,2-trans-2-bromo-2-deoxyglycopyranosyl bromides and fluorides, Application of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, the publication is Synthesis (1993), 889-94, database is CAplus.

Addition of bromine to glycals using quaternary ammonium tribromides as bromine donors is realized with higher stereoselectivities (α-1,2-trans configurated products) compared to bromination with mol. bromine. The reaction is neither sensitive to the solvent nor to the nature of the protecting groups (acetyl, benzoyl, benzyl) of the glycals and very slightly affected by the orientation of the substituents of the different glycals. Some of the α-1,2-trans dibromo adducts have been isolated in 60-75% yields and transformed into the corresponding α-1,2-trans-2-bromo-2-deoxyglycopyranosyl fluorides.

Synthesis published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C6H12N2O, Application of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary