Samath, Sheik A. published the artcileSubstitutions of coordinated salicylaldehyde and its Schiff bases, Safety of 4,5-Dibromo-2-hydroxybenzaldehyde, the main research area is cobalt salicylaldehyde Schiff brominating agent reaction; copper salicylaldehyde Schiff brominating agent reaction; salicylaldehyde Schiff cobalt copper brominating agent; bromination cobalt copper salicylaldehyde Schiff; cyano substitution cobalt copper salicylaldehyde Schiff; succinimido substitution cobalt copper salicylaldehyde Schiff.
Several bis/tris-salicylaldehyde, salicylaldimine and salicylethylenediimine chelates of Co(III), Cr(III), Co(II), Ni(II) and Cu(II) readily react with various brominating agents and undergo α-bromo/cyano/succinimido substitution, with or without accompanying Br substitution of the aryl ring. The selectivity of these reactions on the metal-coordinated salicylaldehyde derivatives allows the preparation in 5-80% yield of hitherto unreported specific α-bromo products. Data are presented for several reactions with Co and Cu complexes. The substituted organic compounds could be isolated by demetalation of the chelate products.
Transition Metal Chemistry (Dordrecht, Netherlands) published new progress about Bromination. 156089-67-7 belongs to class bromides-buliding-blocks, name is 4,5-Dibromo-2-hydroxybenzaldehyde, and the molecular formula is C7H4Br2O2, Safety of 4,5-Dibromo-2-hydroxybenzaldehyde.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary