Crescenzi, Manuela published the artcileIon association and reactivity of the alkali metal salts of alkanoic acids in dipolar aprotic solvents, Recommanded Product: 15-Bromopentadecanoic acid, the main research area is ion association lactonization kinetics; carboxylic acid lactonization alkali metal ion.
The effect of added alkali metal perchlorates on the rate of lactonization of ω-bromoalkanoate ions was investigated in 99% DMSO (4-membered ring formation) and in DMF (4- and 16-membered ring formation). In all cases, the effect of the added metal salts is rate depressing, as a result of the lower reactivity of metal ion-associated species relative to the free ions. Ion-pairing association constants were determined, but the reactivity of ion pairs was so low as to elude direct measurement in most cases. Evidence was also obtained for the formation of ion triplets with Li+ in DMF. The relevance of the present results in connection with the cesium effect is briefly discussed.
Journal of Physical Organic Chemistry published new progress about Alkali metal ions Role: PRP (Properties). 56523-59-2 belongs to class bromides-buliding-blocks, name is 15-Bromopentadecanoic acid, and the molecular formula is C15H29BrO2, Recommanded Product: 15-Bromopentadecanoic acid.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary