《Reductive Cross-Coupling of Aldehydes and Imines Mediated by Visible Light Photoredox Catalysis》 was written by Wang, Rui; Ma, Mengyue; Gong, Xu; Fan, Xinyuan; Walsh, Patrick J.. Name: o-BromobenzaldehydeThis research focused onvicinal amino alc preparation; benzoxazine indolone preparation; iridium photoredox catalyst reductive coupling aryl ketimine aldehyde. The article conveys some information:
In the presence of an iridium photoredox catalyst, aryl ketimines such as 2-BrC6H4N:CPh2 underwent photochem. reductive coupling with aldehydes such as benzaldehyde mediated by N,N-dimethylcyclohexylamine to give di- and triarylamino alcs. such as I. Under photoredox catalysis conditions, the conventional electrophilic reactivity of ketimines is inverted to generate nucleophilic species, allowing reductive coupling with aldehydes. I was converted to benzo-fused morpholine II with a palladium catalyst, while two amino alcs. underwent cyclization and oxidation to yield 3-indolones. In the experiment, the researchers used many compounds, for example, o-Bromobenzaldehyde(cas: 6630-33-7Name: o-Bromobenzaldehyde)
o-Bromobenzaldehyde(cas: 6630-33-7) is used in L-threonine aldolase-catalyzed enantio/diastereoselective aldol reactions.Name: o-BromobenzaldehydeIt is also used in L-threonine aldolase-catalyzed enantio and diastereoselective aldol reactions. Further, it reacts with trichloromethane to prepare 1-(2-bromo-phenyl)-2,2,2-trichloro-ethanol.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary