Recommanded Product: 5-Bromobenzo[d][1,3]dioxoleIn 2020 ,《Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters》 was published in Chemical Science. The article was written by Li, Yahui; Bao, Gao; Wu, Xiao-Feng. The article contains the following contents:
A new palladium-catalyzed intermol. transthioetherification reaction of aryl halides with thioethers and thioesters was developed. The synthetic utility and practicality of this catalytic protocol were demonstrated in a wide range of successful transformations (>70 examples). This catalytic protocol was applicable in carbonylative coupling processes as well, and the first example of carbonylative methylthioesterification of aryl halides was achieved. Notably, this work also provided an approach to using natural products, such as methionine and selenomethionine, as the functional group sources. The experimental part of the paper was very detailed, including the reaction process of 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4Recommanded Product: 5-Bromobenzo[d][1,3]dioxole)
Furthermore, the coupling of 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4) with β-methallyl alcohol was catalyzed by Pd(OAc)2 in combination with P(t-Bu)3.Recommanded Product: 5-Bromobenzo[d][1,3]dioxole
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary