Electric Literature of C7H5BrO2In 2020 ,《Palladium-Catalyzed One-Pot Coupling / Cyclization through Mo(CO)6 as the Carbon Monoxide Donor: Synthesis of Quinazolinones》 appeared in ChemistrySelect. The author of the article were Tao, Shou-Wei; Liu, Rui-Qing; Zhou, Jing-Ya; Zhu, Yong-Ming. The article conveys some information:
An efficient and rapid one-pot synthesis of quinazolinones I (R = Ph, [4-(cyanomethyl)phenyl], 2H-1,3-benzodioxol-5-yl, 3,4,5-trimethoxyphenyl, etc.; R1 = H, 8-Me, 7-Cl, etc.; R2 = H, Me, Ph, 4-fluorophenyl) via a three-component carbonylative coupling of 2-aminobenzamide R1-2-NH2C6H3C(O)NHR2 or 2-aminobenzonitrile, Mo(CO)6 and aryl bromides RBr has been developed recently. This method provide a new way to synthesize quinazolinones I which has a wide substrate scope, good functional group tolerance and mild reaction condition. The experimental process involved the reaction of 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4Electric Literature of C7H5BrO2)
Furthermore, the coupling of 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4) with β-methallyl alcohol was catalyzed by Pd(OAc)2 in combination with P(t-Bu)3.Electric Literature of C7H5BrO2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary