In 2017,Tsuchiya, Shun; Saito, Hayate; Nogi, Keisuke; Yorimitsu, Hideki published 《Manganese-Catalyzed Ring Opening of Benzofurans and Its Application to Insertion of Heteroatoms into the C2-O Bond》.Organic Letters published the findings.Related Products of 7073-94-1 The information in the text is summarized as follows:
A new class of aromatic metamorphosis in which benzofurans are converted into diverse six-membered oxaheterocycles has been developed. This transformation is composed of two reactions in one pot: manganese-catalyzed arylative or alkylative ring-opening of benzofurans affording dianionic intermediates and subsequent trapping with multivalent heteroatom electrophiles. Various electrophiles containing silicon, boron, phosphorus, germanium, and titanium could be applied to this heteroatom insertion. The experimental process involved the reaction of 1-Bromo-2-isopropylbenzene(cas: 7073-94-1Related Products of 7073-94-1)
1-Bromo-2-isopropylbenzene(cas: 7073-94-1) belongs to organobromine compounds.The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides.Related Products of 7073-94-1
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary