《Cobalt-Salen-Based Porous Ionic Polymer: The Role of Valence on Cooperative Conversion of CO2 to Cyclic Carbonate》 was published in ACS Applied Materials & Interfaces in 2020. These research results belong to Li, Jing; Han, Yulan; Lin, Han; Wu, Nanhua; Li, Qinkun; Jiang, Jun; Zhu, Jiahua. Recommanded Product: 1,4-Bis(bromomethyl)benzene The article mentions the following:
Cobalt-salen-based porous ionic polymers, which are composed of cobalt and halogen anions decorated on the framework, effectively catalyze the CO2 cycloaddition reaction of epoxides to cyclic carbonates under ambient conditions. The cooperative effect of bifunctional active sites of cobalt as the Lewis acidic site and the halogen anion as the nucleophile responds to the high catalytic performance. Moreover, d. functional theory results indicate that the cobalt valence state and the corresponding coordination group influence the rate-determining step of the CO2 cycloaddition reaction and the nucleophilicity of halogen anions. In addition to this study using 1,4-Bis(bromomethyl)benzene, there are many other studies that have used 1,4-Bis(bromomethyl)benzene(cas: 623-24-5Recommanded Product: 1,4-Bis(bromomethyl)benzene) was used in this study.
1,4-Bis(bromomethyl)benzene(cas: 623-24-5) belongs to organobromine compounds.Organobromine chemicals are produced naturally by an array of biological and other chemical processes in our environment. Some of these compounds are identical to man-made organobromine compounds, such as methyl bromide, bromoform, and bromophenols, but many others are entirely new moleclar entities, often possessing extraordinary and important biological properties. Recommanded Product: 1,4-Bis(bromomethyl)benzene
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary