Synthesis and Reactivity of Cobalt-Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen was written by Kuriyama, Shogo;Wei, Shenglan;Tanaka, Hiromasa;Konomi, Asuka;Yoshizawa, Kazunari;Nishibayashi, Yoshiaki. And the article was included in Inorganic Chemistry in 2022.Product Details of 128-08-5 This article mentions the following:
A series of cobalt(I)-dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen under ambient reaction conditions to produce up to 371 equiv of silylamine based on the cobalt atom of the catalyst. In the experiment, the researchers used many compounds, for example, 1-Bromopyrrolidine-2,5-dione (cas: 128-08-5Product Details of 128-08-5).
1-Bromopyrrolidine-2,5-dione (cas: 128-08-5) belongs to organobromine compounds. Organo bromine compounds are versatile compounds and are widely used in diverse fields. Organo bromine derivatives are used in the dye sector, as an indicator in analytical chemistry (Bromothymol blue is a popular indicator). The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Product Details of 128-08-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary