3-{[4-(4-Pyridyl)pyrimidin-2-yl]sulfanylmethyl}benzoic acid was written by Zhu, Hai-Bin;Wang, Hai;Ji, Jun-Feng. And the article was included in Acta Crystallographica, Section E: Structure Reports Online in 2008.Quality Control of 3-(Bromomethyl)benzoic acid This article mentions the following:
The title compound, C17H13N3O2S, was prepared by reaction of 4-(4-pyridyl)pyrimidine-2-thiol with 3-(bromomethyl)benzoic acid under basic conditions. Each pair of mols. is mutually linked via O-H…N hydrogen bonds, forming a dimer. The packing of the dimers is stabilized by C-H…锜?interactions involving the methylene unit of the -CH2S- linkage and benzene rings. Crystallog. data are given. In the experiment, the researchers used many compounds, for example, 3-(Bromomethyl)benzoic acid (cas: 6515-58-8Quality Control of 3-(Bromomethyl)benzoic acid).
3-(Bromomethyl)benzoic acid (cas: 6515-58-8) belongs to organobromine compounds. Many of the organo bromine compounds are relatively nonpolar. Bromine is more electronegative than carbon (2.8 vs 2.5) and hence the carbon in a carbon鑱砨romine bond is electrophilic in nature. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Quality Control of 3-(Bromomethyl)benzoic acid
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary