Synthesis and Electrochemical Properties of Donor-Acceptor-Conjugated Polymers Based on Carbazole-EDOT Derivatives with Different Electron-Withdrawing Groups was written by Liu, Junlei;Hou, Weiwei;Xu, Ruoteng;Gao, Yijing;Xu, Lintie;Jiang, Linxiang;Zhang, Cheng. And the article was included in ACS Applied Polymer Materials in 2022.Application In Synthesis of 1-Bromopyrrolidine-2,5-dione This article mentions the following:
A series of donor (D)-acceptor (A)-conjugated monomers (ECzE-NB and ECzE-AQ) were designed and synthesized by EDOT-carbazole-EDOT (ECzE) acting as a donor (D) and anthraquinone (AQ) and nitrobenzene (NB) acting as acceptors (A) in this study. The corresponding polymer films (PECzE, PECzE-NB, and PECzE-AQ) were obtained by electrochem. polymerization, and then the effects of different acceptors on the structure and electrochem. performance of the polymers were studied. Through NMR, mass spectrometry (MS), and Fourier transform IR spectroscopy (FT-IR), it was proved that the monomers were successfully synthesized. The results of the electrochem. performance test illustrated that the electrochem. behavior of PECzE was a typical nondiffusion-controlled process. When the c.d. was 0.1 mA/cm2, the specific capacity of PECzE was 8.41 mF/cm2 with a rather good rate performance. However, the electrochem. behaviors of PECzE-NB and PECzE-AQ were different from that of PECzE owing to the ability of hole injection and spatial structures of the monomers changed by introducing electron-withdrawing groups. In the experiment, the researchers used many compounds, for example, 1-Bromopyrrolidine-2,5-dione (cas: 128-08-5Application In Synthesis of 1-Bromopyrrolidine-2,5-dione).
1-Bromopyrrolidine-2,5-dione (cas: 128-08-5) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Application In Synthesis of 1-Bromopyrrolidine-2,5-dione
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary