Shea, Regan G. et al. published their research in Journal of Organic Chemistry in 1986 | CAS: 28322-40-9

Isopentyltriphenylphosphonium bromide (cas: 28322-40-9) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.HPLC of Formula: 28322-40-9

Allylic selenides in organic synthesis: new methods for the synthesis of allylic amines was written by Shea, Regan G.;Fitzner, Jeffrey N.;Fankhauser, John E.;Spaltenstein, Andreas;Carpino, Philip A.;Peevey, Richard M.;Pratt, Daniel V.;Tenge, Bradley J.;Hopkins, Paul B.. And the article was included in Journal of Organic Chemistry in 1986.HPLC of Formula: 28322-40-9 This article mentions the following:

Oxidative rearrangement of allylic selenides in the presence of various amine nucleophiles provides synthetic access to a variety of allylic amine derivatives The stereochem. outcome of these reactions has been investigated, and is consistent with a [2,3]-sigmatropic rearrangement mechanism. Several D-α-amino acids and racemic β,γ-unsaturated α-amino acids were prepared in this manner. A variant of this process employing an achiral allylic selenide and chiral amide afforded protected allylic amines in low diastereoisomeric excess. In the experiment, the researchers used many compounds, for example, Isopentyltriphenylphosphonium bromide (cas: 28322-40-9HPLC of Formula: 28322-40-9).

Isopentyltriphenylphosphonium bromide (cas: 28322-40-9) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.HPLC of Formula: 28322-40-9

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary