Szostak, Michal published the artcileSelective Reduction of Barbituric Acids Using SmI2/H2O: Synthesis, Reactivity, and Structural Analysis of Tetrahedral Adducts, Recommanded Product: (4-Bromobut-1-yn-1-yl)trimethylsilane, the publication is Angewandte Chemie, International Edition (2013), 52(48), 12559-12563, database is CAplus and MEDLINE.
Monoredn. of barbituric acids using SmI2 was reported. The radicals formed by one-electron reduction of the amide bond have been applied in intramol. additions to alkenes. The cyclic hemiaminal products are analogous to tetrahedral intermediates derived from amide addition reactions and are formed in a formal polarity reversal event.
Angewandte Chemie, International Edition published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C10H15ClO3S, Recommanded Product: (4-Bromobut-1-yn-1-yl)trimethylsilane.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary