Ishi-i, Tsutomu published the artcileReaction of [2.2]Metacyclophanes Having an Internal C:C Bond with Brominating Agents, Product Details of C10H16Br3N, the publication is Journal of Organic Chemistry (1996), 61(15), 5103-5108, database is CAplus.
Treatment of (I) 5-tert-butyl-8-ethenyl[2.2]metacyclophane with benzyltrimethylammonium tribromide or bromine exclusively gave an addition-elimination product II. The bromination reactions of (E)-5-tert-butyl-8-(2-phenylethenyl)[2.2]metacyclophane and its (Z)-isomer were always stereoconvergent to give a mixture (40/60) of β-bromoolefins. On the other hand, when (E)-8,8′-(ethene-1,2-diyl)bis(5-tert-butyl[2.2]metacyclophane) and its (Z)-isomer were treated with the brominating agents, none of the products arising from the electrophilic attack of a bromonium ion on the central etheno bridge was obtained. The reaction of (E)-8,8′-(ethene-1,2-diyl)bis(5-tert-butyl[2.2]metacyclophane) gave a monotetrahydropyrene derivative and a bis-tetrahydropyrene derivative, products resulting from a transannular reaction-alkenyl migration sequence. The reaction pathway of the brominations mentioned above is discussed.
Journal of Organic Chemistry published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Product Details of C10H16Br3N.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary