Wang, Zi-Lu published the artcileCopper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes, Safety of 7-Bromohept-1-yne, the publication is Organic Letters (2020), 22(19), 7735-7742, database is CAplus and MEDLINE.
A Cu-catalyzed anti-Markovnikov hydrosilylation of alkynes with PhSiH3 is reported. This reaction represents a notable and efficient example on Cu-catalyzed hydrosilylation of alkynes, which shows excellent recognition between the terminal and internal triple bonds. Various (hetero)aromatic and aliphatic substituted terminal alkynes underwent this reaction to afford the (E)-vinylsilanes in high yields and with excellent regioselectivity.
Organic Letters published new progress about 81216-14-0. 81216-14-0 belongs to bromides-buliding-blocks, auxiliary class Linker,PROTAC Linker, name is 7-Bromohept-1-yne, and the molecular formula is C8H6ClF3, Safety of 7-Bromohept-1-yne.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary