Fang, Di published the artcileRadical C(sp3)-H Heck-type Reaction of N-Alkoxybenzimidoyl Chlorides with Styrenes to Construct Alkenols, Synthetic Route of 111-83-1, the publication is Organic Letters (2022), 24(10), 2050-2054, database is CAplus and MEDLINE.
The first radical C(sp3)-H Heck-type reaction of aliphatic alcs. for selective δ- and ε-alkenol I [R = H, Ph, 4-FC6H4, etc.; R1 = Me, n-Bu, Bn, etc.; R2 = H, Me; R1R2 = cyclohexyl, cyclopentyl, 2,3-dihydro-1H-inden-2-yl; Ar = Ph, 4-MeC6H4, 4-FC6H4, etc.; X = CH2, O] and II [Ar1 = Ph, 4-CNC6H4, 4-MeOC6H4, etc.] synthesis by photoredox catalysis. N-Alkoxybenzimidoyl chlorides were developed as novel alkoxyl radical precursors with tunable redox potentials. Various alkenols could be constructed by the inert C(sp3)-H Heck-type reaction of 4-cyano-N-alkoxybenzimidoyl chlorides with styrene derivatives under redox-neutral conditions, which could be performed on the gram scale and can be easily derivatized.
Organic Letters published new progress about 111-83-1. 111-83-1 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 1-Bromooctane, and the molecular formula is C8H17Br, Synthetic Route of 111-83-1.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary